Primary study2023
Electrically conductive [Fe4S4]-based organometallic polymers
Kadota K., Chen T., Gormley E.L. et al. · Chemical Science · 2023
Reported here: Alkyl-NHC [Fe4S4] variant products (2-Et, 3-nPr, 4-nBu)
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Kadota K., Chen T., Gormley E.L. et al. · Chemical Science · 2023
Reported here: Alkyl-NHC [Fe4S4] variant products (2-Et, 3-nPr, 4-nBu)
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Raw names, formulas and structural assignments remain separate; no consensus value is inferred.
| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Alkyl-NHC [Fe4S4] variant products (2-Et, 3-nPr, 4-nBu)2023 · Electrically conductive [Fe4S4]-based organometallic polymers | Products from R-BBI-X with R = Et, nPr, nBu and [Fe4S4] precursor; exact formulas not fully establishedIntended [Fe4S4] cluster units. · Ethyl-, n-propyl- and n-butyl-substituted benzobisimidazolylidene NHC linkers. | unknown · PristineSolid products lacked well-defined Bragg peaks by PXRD; longer alkyl chains gave lower yields and nBu gave almost no solid. | 2 · Synthesis and structural characterizations · Fig. S6 |