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1 papers
Bao S.-S., Li N.-Z., Taylor J.M. et al. · Chemistry of Materials · 2015
Reported here: CoCa.2H2O lower-humidity phase
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| CoCa.2H2O lower-humidity phase2015 · Co-Ca Phosphonate Showing Humidity-Sensitive Single Crystal to Single Crystal Structural Transformation and Tunable Proton Conduction Properties | [CoIII CaII(notpH2)(H2O)2]ClO4.2H2O; C9H28N3P3O17ClCoCaCo(III)-Ca(II) phosphonate framework with two coordinated and two lattice water molecules. · notpH2(4-) phosphonate ligand. | 2D · PristineMonoclinic P21/n phase obtained by humidity lowering; framework layer topology remains comparable to CoCa.4H2O but extended H-bond network is interrupted. | main p.4, article p.8119 · Structural Description · Table 1; Figure 1d |