Primary study2021
Macrocycle-Based Metal-Organic Frameworks with NO2-Driven On/Off Switch of Conductivity
Ma Y.-X., Gao B., Li Y. et al. · ACS Applied Materials and Interfaces · 2021
Reported here: MOF A-NO2
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Ma Y.-X., Gao B., Li Y. et al. · ACS Applied Materials and Interfaces · 2021
Reported here: MOF A-NO2
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| MOF A-NO22021 · Macrocycle-Based Metal-Organic Frameworks with NO2-Driven On/Off Switch of Conductivity | ((H3O)4[Co2(L)(DMF)(NO2)12(H2O)4]DMF)Co(II) Co2O11 clusters with BVS values for Co(1) and Co(2) of 2.17 and 2.05. · Calix[4]resorcinarene L8- ligand; adsorbed NO2 bridges Co/carboxylate/H3O+ through hydrogen bonding. | 2D · PristineYellow NO2-loaded crystalline phase, monoclinic P21/m, sandwichlike two-dimensional layer; each NO2 molecule is confined within a cavity. | main p.3 · Results and Discussion · Figure 3 |