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1 papers
Darago L.E., Aubrey M.L., Yu C.J. et al. · Journal of the American Chemical Society · 2015
Reported here: Na3.2(NBu4)1.8Fe2(dhbq)3
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Na3.2(NBu4)1.8Fe2(dhbq)32015 · Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal-Organic Framework | Na3.2(NBu4)1.8Fe2(dhbq)3Fe sites assigned preferentially as high-spin FeIII, although one site could possibly be low-spin FeII. · More strongly reduced dhbq framework, interpreted as ligand-based reduction generating dhbq3- and then thb4- ligands. | 3D · PristineStrongly reduced derivative with PXRD almost overlaying 1; formula is putative due to unsuccessful C/H/N analysis. | S-3 · Experimental Details · Figure S4 |