Primary study2022
Bromine Vapor Induced Continuous p- to n-Type Conversion of a Semiconductive Metal-Organic Framework Cu[Cu(pdt)2]
Gupta S., Tanaka H., Sato T. et al. · Inorganic Chemistry · 2022
Reported here: Brx@Cu[Cu(pdt)2]
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1 papers
Gupta S., Tanaka H., Sato T. et al. · Inorganic Chemistry · 2022
Reported here: Brx@Cu[Cu(pdt)2]
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Brx@Cu[Cu(pdt)2]2022 · Bromine Vapor Induced Continuous p- to n-Type Conversion of a Semiconductive Metal-Organic Framework Cu[Cu(pdt)2] | Brx@Cu[Cu(pdt)2], represented by authors as Brx-@CuII[CuII(pdt)2]1-x[CuIII(pdt)2]x for the segregated semiconductive stateCopper centres partially oxidised from CuII to CuIII in the Cu(pdt)2 moiety · 2,3-pyrazinedithiolate (pdt) | 3D · PristineBromine-loaded/doped isomorphic derivative of Cu[Cu(pdt)2] with retained crystallinity and continuously shortened c axis with increasing x. | 2-3 · Results and Discussion · Figure 2; Table S1 |