Thermoelectric — Bromine Vapor Induced Continuous p- to n-Type Conversion of a Semiconductive Metal-Organic Framework Cu[Cu(pdt)2]

Measurement evidence

Thermoelectric

Bromine Vapor Induced Continuous p- to n-Type Conversion of a Semiconductive Metal-Organic Framework Cu[Cu(pdt)2] · Gupta S., Tanaka H., Sato T. et al. · Inorganic Chemistry · 2022 · 4414-4420

1 measurement group · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Thermoelectromotive-force measurement on pressed pellets

Brx@Cu[Cu(pdt)2] bromine-doped series · Powder

Home-built apparatus with Peltier heating/cooling, Al blocks, T-type thermocouples, Agilent 34420A nanovolt/microohm meter; S = -DeltaV/DeltaT.

Temperature: ambient temperature
Atmosphere: ambient
Geometry: pressed pellet bridging aluminium blocks; copper/constantan thermocouples fixed by carbon paste
Context: pristine and Br-doped pellets
Measurement source: S7-S8 · Experimental details of thermoelectromotive force measurement · Figure S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Bromine fraction at p-to-n Seebeck sign boundary	sign changed at x = 0.5; negative when x > 0.5	—	—	Text Rounded Reported	5 · Thermoelectric Properties · Figure 6b
Seebeck coefficient x = 0	+337 uV K-1	—	—	Text Exact Reported	4 · Thermoelectric Properties · Figure 6
Seebeck coefficient x = 0.10	~190 uV K-1 from Figure 6b	—	—	Figure Axis Approximate	5 · Thermoelectric Properties · Figure 6b
Seebeck coefficient x = 0.44	~5 uV K-1 from Figure 6b	—	—	Figure Axis Approximate	5 · Thermoelectric Properties · Figure 6b
Seebeck coefficient x = 0.62	~-25 uV K-1 from Figure 6b	—	—	Figure Axis Approximate	5 · Thermoelectric Properties · Figure 6b
Seebeck coefficient x = 0.94	~-105 uV K-1 from Figure 6b	—	—	Figure Axis Approximate	5 · Thermoelectric Properties · Figure 6b