Electrochemistry Application — Bromine Vapor Induced Continuous p- to n-Type Conversion of a Semiconductive Metal-Organic Framework Cu[Cu(pdt)2]

Measurement evidence

Electrochemistry Application

Bromine Vapor Induced Continuous p- to n-Type Conversion of a Semiconductive Metal-Organic Framework Cu[Cu(pdt)2] · Gupta S., Tanaka H., Sato T. et al. · Inorganic Chemistry · 2022 · 4414-4420

1 measurement group · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Literature cyclic voltammetry/redox potentials cited for thermodynamic argument

[Cu(pdt)2] model species · Model

Not measured first-hand in this paper; values cited from Robira et al., Kobayashi et al., and CRC electrochemical series.

Geometry
literature context only
Context
Cu(pdt)2 redox species and Br2/Br- couple
Measurement source
3 · Results and Discussion
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Bromine reduction potentialE0 = 1.066 V vs SHE for Br2(l) + 2e- -> 2Br-Text
Exact Reported
3 · Results and Discussion
Literature solid-state CV of Cu[Cu(pdt)2]E1/2 = -0.65 V vs Ag/Ag+Text
Exact Reported
3 · Results and Discussion
Literature CuII/CuIII E1/2 of TBA-[CuIII(pdt)2] vs Ag/AgClE1/2 = -0.33 V vs Ag/AgClText
Exact Reported
3 · Results and Discussion
Literature CuII/CuIII E1/2 of TBA-[CuIII(pdt)2] vs SHEca. -0.13 V vs SHEText
Approximate
3 · Results and Discussion