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1 papers
Bao S.-S., Li N.-Z., Taylor J.M. et al. · Chemistry of Materials · 2015
Reported here: CoCa.nH2O layered cobalt-calcium phosphonate
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| CoCa.nH2O layered cobalt-calcium phosphonate2015 · Co-Ca Phosphonate Showing Humidity-Sensitive Single Crystal to Single Crystal Structural Transformation and Tunable Proton Conduction Properties | [CoIII CaII(notpH2)(H2O)2]ClO4.nH2OHeterometallic Co(III)-Ca(II) nodes; Co is octahedral CoO3N3 and Ca is distorted octahedral CaO6. · notpH2(4-) derived from notpH6 = 1,4,7-triazacyclononane-1,4,7-triyl-tris(methylenephosphonic acid), C9H18N3(PO3H2)3. | 2D · PristineLayered 2D phosphonate framework with positively charged layers balanced by interlayer ClO4- anions and lattice water; reversible hydration states n = 0, 2, 3, 4 are discussed. | main p.1, article p.8116 · Abstract |