Primary study2025
Mixed proton-electron conductivity in a dynamic 3D metal-organic framework
Rambabu D., Goossens T., Bakuru V.R. et al. · Chem · 2025
Reported here: H12-M2-(DOBDP)3 MOF family
Reported material
H12-M2-(DOBDP)3 MOF family
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1primary papers
1material records
3linked samples
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2025–2025publication span
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| H12-M2-(DOBDP)3 MOF family2025 · Mixed proton-electron conductivity in a dynamic 3D metal-organic framework | H12-M2-(DOBDP)3, M(III) = Fe, Al, Sc, In; H6-DOBDP = 2,5-dihydroxy-1,4-benzenediphosphonic acidTrivalent metal nodes octahedrally coordinated to six phosphonate groups; [M(O2P-OH)3]n one-dimensional chain-like SBUs along c. · H4-DOBDP2- / 2,5-dihydroxy-1,4-benzenediphosphonate with uncoordinated P-OH and hydroquinone/phenolate groups | 3D · PristinePorous honeycomb-type hexagonal 3D framework; Fe and Al single-crystal phases in trigonal P-3c1; hydrated/dehydrated phases can distort to triclinic P-1. | p002-p003 · Summary; Synthesis and physicochemical analysis |