Primary study2020
Synthesis of a copper 1,3,5-triamino-2,4,6-benzenetriol metal-organic framework
Jiang Y., Oh I., Joo S.H. et al. · Journal of the American Chemical Society · 2020
Reported here: Mixed-valence pristine Cu3(TABTO)2 model
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Mixed-valence pristine Cu3(TABTO)2 model
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2020–2020publication span
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Mixed-valence pristine Cu3(TABTO)2 model2020 · Synthesis of a copper 1,3,5-triamino-2,4,6-benzenetriol metal-organic framework | Cu3(TABTO)2 with Cu(NH2)2O2 and Cu(NH2)(NH)O2 subunitsMixture of square-planar Cu(II)-like and trigonal-planar Cu(I)-like sites · Partly oxidised TABTO-derived ligand | 2D · Model SystemDFT model closer to experimental pristine Cu3(TABTO)2 with mixed square-planar/trigonal-planar subunits. | S23 · Explanations of structure and electrical conductivity · Figure S14 |