Primary study2017
Electrical semiconduction modulated by light in a cobalt and naphthalene diimide metal-organic framework
Castaldelli E., Imalka Jayawardena K.D.G., Cox D.C. et al. · Nature Communications · 2017
Reported here: MOF-CoNDI-py-2
Reported material
MOF-CoNDI-py-2
This group combines only harmless case, dash and spacing variants of the reported identity. It does not assert a broader chemical equivalence without source review.
1primary papers
1material records
2linked samples
14linked measurements
37linked results
2017–2017publication span
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Diffraction Structure1 paper2 measurements · 14 resultsElectrical Transport1 paper4 measurements · 11 resultsElectrochemistry Application1 paper1 measurement · 3 resultsMicroscopy Morphology1 paper1 measurement · 0 resultsOther1 paper1 measurement · 2 resultsPorosity1 paper1 measurement · 3 resultsSpectroscopy1 paper4 measurements · 4 results
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| MOF-CoNDI-py-22017 · Electrical semiconduction modulated by light in a cobalt and naphthalene diimide metal-organic framework | C27H19.5Co1.5N3O9.25 empirical formula from SI Table 3Co(II) centres; two crystallographically independent high-spin Co(II) atoms in a trinuclear cobalt fragment · N,N'-bis(4-pyridyl)-1,4,5,8-naphthalene diimide (NDI-py) and terephthalate (TpA); coordinated/included DMF and water/solvent modelled | 3D · PristineCrystalline monoclinic C2/c framework, CCDC 1517923; NDI-py molecules are oriented in layered fashion and PXRD matches the simulated pattern with preferred-orientation differences. | 2-3 · Results - Synthesis of MOF-CoNDI-py-2 · Fig. 1; Fig. 3 |