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1 papers
Darago L.E., Aubrey M.L., Yu C.J. et al. · Journal of the American Chemical Society · 2015
Reported here: Na0.9(NBu4)1.8FeIII2(dhbq)3 (2)
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Na0.9(NBu4)1.8FeIII2(dhbq)3 (2)2015 · Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal-Organic Framework | Na0.9(NBu4)1.8FeIII2(dhbq)3; calculated C46.8H70.8Fe2N1.8Na0.9O12High-spin FeIII centres retained after reduction. · Reduced mixed-valent dhbq linkers; charge balance gives about 2.7:0.3 dhbq3-:dhbq2- ratio. | 3D · PristinePost-synthetically reduced derivative of 1; PXRD almost overlays with simulated 1, indicating little unit-cell change. | 4 · Chemical Reduction of 1 · Figure S3 |