Electrical Transport — Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal-Organic Framework

2 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Pressed pellet of 1 · Pellet

Home-built two-electrode screw cell, contact area 0.04757 cm2; I-V profiles collected with Bio-Logic SP200; Ohm's law used to determine sigma.

Temperature: 70-300
Atmosphere: airtight sealed cell prepared in Ar glovebox
Geometry: Pressed pellet between polished copper rods; +/-1 V window
Context: Pristine framework 1
Measurement source: S-5 · Variable Temperature Two-Point Electronic Conductivity · Figures 7, S7, S8

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Room-temperature conductivity of 1Marked as a best value within this paper	0.16(1) S/cm at 298 K	—	(1)	Text Exact Reported	5 · Electronic Conductivity · Figure 7
Arrhenius activation energy of 1Marked as a best value within this paper	110 meV	—	—	Text Rounded Reported	6 · Electronic Conductivity · Figures 7, S7, S8
Approximate low-temperature conductivity of 1	log10(sigma) about -9.1 at 70 K	—	visual estimate from Figure 7	Figure Axis Approximate	6 · Electronic Conductivity · Figure 7
Ohmic I-V range for 1	Ohmic between +1 and -1 V; similar linearity down to 60 K	—	—	Caption Exact Reported	S-16 · Figure S8 caption · Figure S8

Pressed pellet of 2 · Pellet

Home-built two-electrode screw cell, contact area 0.04757 cm2; I-V profiles collected with Bio-Logic SP200; Ohm's law used to determine sigma.

Temperature: 90-300
Atmosphere: airtight sealed cell prepared in Ar glovebox
Geometry: Pressed pellet between polished copper rods; +/-1 V window
Context: Na-inserted reduced framework 2
Measurement source: S-5 · Variable Temperature Two-Point Electronic Conductivity · Figures 7, S7, S9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Room-temperature conductivity of 2	0.0062(1) S/cm at 298 K	—	(1)	Text Exact Reported	5 · Electronic Conductivity · Figure 7
Arrhenius activation energy of 2	180 meV	—	—	Text Rounded Reported	6 · Electronic Conductivity · Figures 7, S7-S9
Approximate low-temperature conductivity of 2	log10(sigma) about -9.1 at 90 K	—	visual estimate from Figure 7	Figure Axis Approximate	6 · Electronic Conductivity · Figure 7
Ohmic I-V range for 2	Ohmic between +1 and -1 V; similar linearity down to 90 K	—	—	Caption Exact Reported	S-17 · Figure S9 caption · Figure S9