Electrochemistry Application — Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal-Organic Framework

Measurement evidence

Electrochemistry Application

Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal-Organic Framework · Darago L.E., Aubrey M.L., Yu C.J. et al. · Journal of the American Chemical Society · 2015 · 15703-15711

1 measurement group · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Slow-scan cyclic voltammetry

Composite electrochemical electrode containing 1 · Electrode

Lithium reference and counter electrodes; 0.1 M LiBF4 in propylene carbonate; scan rate 30 microV/s; argon-filled glovebox.

Atmosphere: Ar glovebox
Geometry: Airtight three-electrode Swagelok PFA cell; composite electrode on carbon cloth
Context: Composite electrode containing pristine framework 1
Measurement source: 4 · Slow-Scan Cyclic Voltammetry · Figure 4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Faradaic efficiency for electrochemical reduction	77% Faradaic efficiency	—	—	Text Rounded Reported	3 · Slow-Scan Cyclic Voltammetry · Figure 4
Integrated first quasi-reversible peak	1.1 electrons per mole of 1	—	—	Text Rounded Reported	4 · Slow-Scan Cyclic Voltammetry · Figure 4
Total observed electrochemical reduction activity	close to 4 e- per mole of 1	—	close to	Text Approximate	4 · Slow-Scan Cyclic Voltammetry · Figure 4
Maximum quasi-reversible electrochemical reduction stoichiometry	Lix[NBu4]2FeIII2(dhbq)3 reduced to x = 3.7 quasi-reversibly	—	—	Text Rounded Reported	3 · Slow-Scan Cyclic Voltammetry · Figure 4