Porosity — Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal-Organic Framework

Measurement evidence

Porosity

Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal-Organic Framework · Darago L.E., Aubrey M.L., Yu C.J. et al. · Journal of the American Chemical Society · 2015 · 15703-15711

1 measurement group · 3 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

77 K N2 and 195 K CO2 adsorption isotherms

Microcrystalline/crystalline powder of 1 · Powder

Solid samples heated under vacuum at 150 C for 1 h before adsorption measurements.

Temperature
77; 195
Atmosphere
N2 and CO2 adsorbates
Geometry
Powder adsorption isotherm
Context
Pristine framework 1
Measurement source
S-8 · Figure S1 caption · Figure S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Approximate 195 K CO2 uptake at high pressure for 1about 0.83 mmol/g at P about 0.96 barvisual estimate from Figure S1Figure Axis
Approximate
S-8 · Figure S1 · Figure S1
Microporosity of 1 after activationlack of microporosity / nonexistent microporosityText
Qualitative
3 · Results and Discussion · Figure S1
Approximate 77 K N2 uptake at high pressure for 1about 0.43 mmol/g at P about 0.98 barvisual estimate from Figure S1Figure Axis
Approximate
S-8 · Figure S1 · Figure S1