Other — Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal-Organic Framework

Measurement evidence

Other

Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal-Organic Framework · Darago L.E., Aubrey M.L., Yu C.J. et al. · Journal of the American Chemical Society · 2015 · 15703-15711

1 measurement group · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

SQUID dc/ac magnetic susceptibility and hysteresis

Microcrystalline/crystalline powder of 1 · Powder

Samples in quartz tubes with eicosane; dc susceptibility 2-300 K at 0.1, 0.5 and 1 T; hysteresis sweep rate 2 mT/s.

Temperature
2-300
Atmosphere
sealed under static vacuum after Schlenk evacuation
Geometry
Powder in quartz tube with eicosane
Context
Pristine 1 and reduced 2
Measurement source
S-6 · Magnetic Measurements · Figures 8, S10-S12
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Room-temperature chi_M T for 110.9 emu K/mol at 300 KText
Rounded Reported
6 · Magnetic Properties · Figure 8
Room-temperature chi_M T for 211.2 emu K/mol at 300 KText
Rounded Reported
6 · Magnetic Properties · Figure 8
Coercive field of 1100 OeText
Rounded Reported
6 · Magnetic Properties · Figure 8
Coercive field of 2350 OeText
Rounded Reported
6 · Magnetic Properties · Figure 8
Curie constant for 1C = 6.1 emu K/molText
Rounded Reported
6 · Magnetic Properties · Figure 8
Curie constant for 2C = 5.90 emu K/molText
Rounded Reported
6 · Magnetic Properties · Figure 8
Curie-Weiss theta for 1theta = 134 KText
Rounded Reported
6 · Magnetic Properties · Figure 8
Curie-Weiss theta for 2theta = 144 KText
Rounded Reported
6 · Magnetic Properties · Figure 8
Magnetic ordering temperature of 18 KText
Rounded Reported
6 · Magnetic Properties · Figures 8 and S10
Magnetic ordering temperature of 212 KText
Rounded Reported
6 · Magnetic Properties · Figure S10
Low-temperature saturation magnetization of 17.3 muB/molText
Rounded Reported
6 · Magnetic Properties · Figure S11
Low-temperature saturation magnetization of 27.11 muB/molText
Exact Reported
7 · Magnetic Properties · Figure S12