Primary study2021
A New Electrically Conducting Metal–Organic Framework Featuring U-Shaped cis-Dipyridyl Tetrathiafulvalene Ligands
Gordillo M.A., Benavides P.A., Spalding K. et al. · Frontiers in Chemistry · 2021
Reported here: sine-MOF
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Gordillo M.A., Benavides P.A., Spalding K. et al. · Frontiers in Chemistry · 2021
Reported here: sine-MOF
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| sine-MOF2021 · A New Electrically Conducting Metal–Organic Framework Featuring U-Shaped cis-Dipyridyl Tetrathiafulvalene Ligands | [Zn2(DPTTF)TCPB*3DMA]n; activated pristine elemental-analysis formula reported as Zn2C52H37O10.5S4N2; I2-treated empirical formula Zn2C55H50O14S4N2I1.5Zn2(COO)4 paddlewheel nodes · 1,2,4,5-tetrakis-(4-carboxyphenyl)benzene (TCPB) and U-shaped Z-DPTTF (cis-dipyridyl tetrathiafulvalene) | 3D · PristineOrthorhombic Pnma 3D framework in which twisted TCPB forms Zn2(COO)4 paddlewheel nodes and U-shaped Z-DPTTF ligands bridge adjacent nodes in an alternating sine-wave arrangement along the b axis. | 2 · Results and Discussion · Figure 1 |