Electrochemistry Application — A New Electrically Conducting Metal–Organic Framework Featuring U-Shaped cis-Dipyridyl Tetrathiafulvalene Ligands

3 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

solid-state cyclic voltammetry (CV)

Voltammetry

I2-treated sine-MOF powder · Powder

Pastes made in MeCN mounted on glassy carbon working electrode; Ag/AgCl reference electrode, Pt-mesh counter electrode, 0.1 M Bu4NPF6 in MeCN.

Geometry: MOF paste on glassy carbon electrode
Context: I2-treated framework compared with pristine control
Measurement source: 4 · Optical and Electrochemical Properties of sine-MOF · Figure 5B

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
I2-treated first anodic peak	0.79 V vs Ag/AgCl	—	—	Text Exact Reported	3 · Optical and Electrochemical Properties of sine-MOF · Figure 5B
I2-treated second anodic peak	1.05 V vs Ag/AgCl	—	—	Text Exact Reported	3 · Optical and Electrochemical Properties of sine-MOF · Figure 5B

solid-state cyclic voltammetry (CV)

Voltammetry

pristine sine-MOF evacuated powder · Powder

Pastes made in MeCN mounted on glassy carbon working electrode; Ag/AgCl reference electrode, Pt-mesh counter electrode, 0.1 M Bu4NPF6 in MeCN.

Geometry: MOF paste on glassy carbon electrode
Context: pristine framework
Measurement source: 1 · General Materials and Methods

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
pristine first anodic peak	0.68 V vs Ag/AgCl	—	—	Text Exact Reported	3 · Optical and Electrochemical Properties of sine-MOF · Figure 5A
pristine second anodic peak	0.96 V vs Ag/AgCl	—	—	Text Exact Reported	3 · Optical and Electrochemical Properties of sine-MOF · Figure 5A

square wave voltammetry (SWV)

Voltammetry

pristine sine-MOF evacuated powder · Powder

SWV of pristine and I2-doped sine-MOF vs Ag/AgCl in 0.1 M Bu4NPF6/MeCN; paired comparison in Supplementary Figure S4 main text and SI caption Figure S2.

Geometry: MOF paste electrode
Context: pristine and I2-treated frameworks
Measurement source: 2 · Supplementary Figures and tables · Figure S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
SWV redox-process count	two stepwise one-electron oxidation processes of DPTTF to DPTTF*+ and DPTTF2+	—	—	Caption Qualitative	2 · Supplementary Figures and tables · Figure S2