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1 papers
Hu Y.-Q., Li M.-Q., Wang Y. et al. · Chemistry - A European Journal · 2017
Reported here: {[Tb(Cu4I4)(ina)3(DMF)].1.5I2}n, I2@1
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| {[Tb(Cu4I4)(ina)3(DMF)].1.5I2}n, I2@12017 · Direct Observation of Confined I−⋅⋅⋅I2⋅⋅⋅I− Interactions in a Metal–Organic Framework: Iodine Capture and Sensing | {[Tb(Cu4I4)(ina)3(DMF)].1.5I2}n; EA formula C21H19Cu4I7N4O7Tb; crystallographic formula C42H38Cu8I14N8O14Tb2{Cu4I4}n chains interacting with guest I2 to give a quasi-{Cu4I5}n layer through I-...I2...I- contacts · ina = isonicotinate | 3D · PristineIodine-loaded framework retaining crystallinity; I2 occupies channels A and B, with channel A forming a linear I-...I2...I- polyiodide arrangement. | p002-p004 / article p.8410-8412 · Main text · Figure 1; Figure 4; Figure S10-S11 |