Electrochemistry Application — Conductive Metal–Organic Framework Nanowire Array Electrodes for High-Performance Solid-State Supercapacitors

Measurement evidence

Electrochemistry Application

Conductive Metal–Organic Framework Nanowire Array Electrodes for High-Performance Solid-State Supercapacitors · Li W.-H., Ding K., Tian H.-R. et al. · Advanced Functional Materials · 2017 · 1702067

19 measurement groups · 28 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry

Blank carbon fibre paper electrode · Electrode

Blank carbon paper in three-electrode 3 M KCl cell; -0.4 to +0.4 V vs Ag/AgCl at 100 mV s-1.

Atmosphere
3 M KCl aqueous electrolyte
Geometry
three-electrode cell
Context
Substrate-only control
Measurement source
p.7 · Figures, Tables and related discussion · Figure S6
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
blank carbon paper capacitance contributionalmost no contribution to capacitanceText
Qualitative
p.3 · Supercapacitors Performance · Figure S6b

Specific capacitance in three-electrode cell

Cu-CAT powder slurry electrode on carbon fibre paper · Electrode

Cu-CAT powder/PVDF electrode in 3 M KCl, no conductive carbon additive; Table S1 value at 50 mV s-1.

Atmosphere
3 M KCl aqueous electrolyte
Geometry
three-electrode cell
Context
Cu-CAT powder/PVDF/carbon paper control
Measurement source
p.15 · Table S1 · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu-CAT powder specific capacitance at 50 mV s-1Marked as a best value within this paper35 F g-1SI Table
Exact Reported
p.15 · Table S1 · Table S1
Cu-CAT powder electrode capacitance at 10 A g-1 from Figure 3dapproximately 17 F g-1 by visual readFigure Axis
Approximate
p.4 · Supercapacitors Performance · Figure 3d
Cu-CAT powder electrode rate retention, 0.5 to 10 A g-1approximately 33%Text
Approximate
p.3 · Supercapacitors Performance · Figure 3d

Specific capacitance in three-electrode cell

MIL-100 powder slurry electrode without conductive carbon · Electrode

Powder/PVDF electrode without conductive carbon additive measured in 3 M KCl at 50 mV s-1; carbon fibre paper current collector.

Atmosphere
3 M KCl aqueous electrolyte
Geometry
three-electrode cell; Ag/AgCl reference and Pt counter
Context
MIL-100 powder/PVDF/carbon paper control
Measurement source
p.15 · Table S1 · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
MIL-100 specific capacitance at 50 mV s-10.036 F g-1SI Table
Exact Reported
p.15 · Table S1 · Table S1

Specific capacitance in three-electrode cell

MIL-101 powder slurry electrode without conductive carbon · Electrode

Powder/PVDF electrode without conductive carbon additive measured in 3 M KCl at 50 mV s-1; carbon fibre paper current collector.

Atmosphere
3 M KCl aqueous electrolyte
Geometry
three-electrode cell; Ag/AgCl reference and Pt counter
Context
MIL-101 powder/PVDF/carbon paper control
Measurement source
p.15 · Table S1 · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
MIL-101 specific capacitance at 50 mV s-10.021 F g-1SI Table
Exact Reported
p.15 · Table S1 · Table S1

Specific capacitance in three-electrode cell

UiO-66 powder slurry electrode without conductive carbon · Electrode

Powder/PVDF electrode without conductive carbon additive measured in 3 M KCl at 50 mV s-1; carbon fibre paper current collector.

Atmosphere
3 M KCl aqueous electrolyte
Geometry
three-electrode cell; Ag/AgCl reference and Pt counter
Context
UiO-66 powder/PVDF/carbon paper control
Measurement source
p.15 · Table S1 · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
UiO-66 specific capacitance at 50 mV s-10.008 F g-1SI Table
Exact Reported
p.15 · Table S1 · Table S1

Specific capacitance in three-electrode cell

ZIF-67 powder slurry electrode without conductive carbon · Electrode

Powder/PVDF electrode without conductive carbon additive measured in 3 M KCl at 50 mV s-1; carbon fibre paper current collector.

Atmosphere
3 M KCl aqueous electrolyte
Geometry
three-electrode cell; Ag/AgCl reference and Pt counter
Context
ZIF-67 powder/PVDF/carbon paper control
Measurement source
p.15 · Table S1 · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ZIF-67 specific capacitance at 50 mV s-10.133 F g-1SI Table
Exact Reported
p.15 · Table S1 · Table S1

Specific capacitance in three-electrode cell

ZIF-8 powder slurry electrode without conductive carbon · Electrode

Powder/PVDF electrode without conductive carbon additive measured in 3 M KCl at 50 mV s-1; carbon fibre paper current collector.

Atmosphere
3 M KCl aqueous electrolyte
Geometry
three-electrode cell; Ag/AgCl reference and Pt counter
Context
ZIF-8 powder/PVDF/carbon paper control
Measurement source
p.15 · Table S1 · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ZIF-8 specific capacitance at 50 mV s-10.002 F g-1SI Table
Exact Reported
p.15 · Table S1 · Table S1

Electrochemical impedance spectroscopy

Cu-CAT nanowire arrays on carbon fibre paper · Electrode

Nyquist spectra measured with CompactStat-Plus2 from 0.01 to 1000000 Hz; compared with Cu-CAT powder electrode.

Atmosphere
3 M KCl aqueous electrolyte
Geometry
three-electrode cell
Context
Binder-free Cu-CAT NWA electrode
Measurement source
p.3, p.6 · Supercapacitors Performance; Characterization · Figure 3e; Figure S8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu-CAT NWA charge-transfer resistance0.5 ohmText
Exact Reported
p.3 · Supercapacitors Performance · Figure 3e
Cu-CAT NWA ohmic resistance1.2 ohmText
Exact Reported
p.3 · Supercapacitors Performance · Figure 3e

Electrochemical impedance spectroscopy

Cu-CAT powder slurry electrode on carbon fibre paper · Electrode

Nyquist spectra of Cu-CAT powder slurry electrode compared with Cu-CAT NWA electrode.

Atmosphere
3 M KCl aqueous electrolyte
Geometry
three-electrode cell
Context
Cu-CAT powder/PVDF/carbon paper control
Measurement source
p.3 · Supercapacitors Performance · Figure 3e; Figure S8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu-CAT powder electrode charge-transfer resistance7.4 ohmText
Exact Reported
p.3 · Supercapacitors Performance · Figure 3e
Cu-CAT powder electrode ohmic resistance3.6 ohmText
Exact Reported
p.3 · Supercapacitors Performance · Figure 3e

LED demonstration

Symmetric solid-state supercapacitor with Cu-CAT NWA electrodes · Electrode

Three series-connected Cu-CAT NWA devices powered a 1.5 V red LED for more than 60 s.

Geometry
three solid-state devices connected in series
Context
Cu-CAT NWA device demonstration
Measurement source
p.5 · Supercapacitors Performance · Figure 4f
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
LED powered durationmore than 60 sText
Approximate
p.5 · Supercapacitors Performance · Figure 4f
red LED voltage1.5 VText
Exact Reported
p.5 · Supercapacitors Performance · Figure 4f

Two-electrode solid-state cyclic voltammetry

Symmetric solid-state supercapacitor with Cu-CAT NWA electrodes · Electrode

Symmetric Cu-CAT NWA device with PVA/KCl gel; scan rates 5, 10, 20, 50 and 100 mV s-1; about 0-0.8 V window.

Atmosphere
PVA/KCl gel electrolyte
Geometry
two-electrode symmetric solid-state device
Context
Cu-CAT NWA electrodes with gel electrolyte
Measurement source
p.5 · Supercapacitors Performance · Figure 4a
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu-CAT NWA solid-state CV current density at 100 mV s-1approximately +/-3.5 A g-1 by visual readFigure Axis
Approximate
p.5 · Supercapacitors Performance · Figure 4a

Cycling stability

Symmetric solid-state supercapacitor with Cu-CAT NWA electrodes · Electrode

Symmetric Cu-CAT NWA solid-state device cycled for 5000 cycles at 50 mV s-1.

Atmosphere
PVA/KCl gel electrolyte
Geometry
two-electrode symmetric solid-state device
Context
Cu-CAT NWA electrodes with gel electrolyte
Measurement source
p.4 · Supercapacitors Performance · Figure 4c; Figure S11
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu-CAT NWA solid-state cycling retentionmore than 85% after 5000 cycles at 50 mV s-1Text
Approximate
p.4 · Supercapacitors Performance · Figure 4c

Ragone energy/power density

Symmetric solid-state supercapacitor with Cu-CAT NWA electrodes · Electrode

Energy and power density calculated for Cu-CAT NWA symmetric solid-state supercapacitor; SI Figure S13 provides Ragone plot.

Atmosphere
PVA/KCl gel electrolyte
Geometry
two-electrode symmetric solid-state device
Context
Cu-CAT NWA electrodes with gel electrolyte
Measurement source
p.5 · Supercapacitors Performance · Figure S13
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu-CAT NWA solid-state energy densityapproximately 2.6 W h kg-1Text
Approximate
p.5 · Supercapacitors Performance · Figure S13
Cu-CAT NWA solid-state power density conditionapproximately 0.2 kW kg-1Text
Approximate
p.5 · Supercapacitors Performance · Figure S13

Two-electrode solid-state galvanostatic charge/discharge

Symmetric solid-state supercapacitor with Cu-CAT NWA electrodes · Electrode

Symmetric Cu-CAT NWA device with PVA/KCl gel; current densities 0.25, 0.5, 1.0, 2.5 and 5.0 A g-1.

Atmosphere
PVA/KCl gel electrolyte
Geometry
two-electrode symmetric solid-state device
Context
Cu-CAT NWA electrodes with gel electrolyte
Measurement source
p.4-5 · Supercapacitors Performance · Figure 4b
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu-CAT NWA solid-state surface-area-normalised capacitanceMarked as a best value within this paperapproximately 22 uF cm-2Text
Approximate
p.5 · Supercapacitors Performance · Figure 4d; Table S2
Cu-CAT NWA solid-state device specific capacitanceMarked as a best value within this paper120 F g-1 at 0.5 A g-1Text
Exact Reported
p.4 · Supercapacitors Performance · Figure 4b; Table S2

Rate performance

Symmetric solid-state supercapacitor with Cu-CAT NWA electrodes · Electrode

Rate retention from 0.25 to 5 A g-1 compared between Cu-CAT NWA and Cu-CAT powder devices; NWA loadings 0.50 and 2.01 mg cm-2.

Atmosphere
PVA/KCl gel electrolyte
Geometry
two-electrode symmetric solid-state device
Context
Cu-CAT NWA electrodes with gel electrolyte
Measurement source
p.5 · Supercapacitors Performance · Figure 4e; Figure S12
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu-CAT NWA solid-state rate retention at 0.50 mg cm-2 loading55% from 0.25 to 5 A g-1Text
Exact Reported
p.5 · Supercapacitors Performance · Figure 4e
Cu-CAT NWA solid-state rate retention at 2.01 mg cm-2 loading45% from 0.25 to 5 A g-1Text
Exact Reported
p.5 · Supercapacitors Performance · Figure S12

Rate performance

Symmetric solid-state supercapacitor with Cu-CAT powder electrodes · Electrode

Cu-CAT powder-based solid-state capacitor rate retention from 0.25 to 5 A g-1.

Atmosphere
PVA/KCl gel electrolyte
Geometry
two-electrode symmetric solid-state device
Context
Cu-CAT powder/PVDF control device
Measurement source
p.5 · Supercapacitors Performance · Figure 4e
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu-CAT powder solid-state rate retention23% from 0.25 to 5 A g-1Text
Exact Reported
p.5 · Supercapacitors Performance · Figure 4e

Cyclic voltammetry

Cu-CAT nanowire arrays on carbon fibre paper · Electrode

Cu-CAT NWA electrode in three-electrode 3 M KCl aqueous cell; scan rates 10, 20, 50, 100, 200 and 500 mV s-1 in Figure 3a.

Atmosphere
3 M KCl aqueous electrolyte
Geometry
three-electrode cell; Ag/AgCl reference and Pt counter
Context
Binder-free Cu-CAT NWA electrode on carbon fibre paper
Measurement source
p.3-4 · Supercapacitors Performance · Figure 3a
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource

Cycling stability

Cu-CAT nanowire arrays on carbon fibre paper · Electrode

Cu-CAT NWA electrode cycled 5000 times at 800 mV s-1.

Atmosphere
3 M KCl aqueous electrolyte
Geometry
three-electrode cell
Context
Binder-free Cu-CAT NWA electrode
Measurement source
p.3 · Supercapacitors Performance · Figure 3c; Figure S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu-CAT NWA capacitance retention after cycling80% after 5000 cycles at 800 mV s-1Text
Exact Reported
p.3 · Supercapacitors Performance · Figure 3c

Galvanostatic charge/discharge

Cu-CAT nanowire arrays on carbon fibre paper · Electrode

Three-electrode cell in 3 M KCl; current densities 0.5, 1.0, 2.0, 5.0 and 10.0 A g-1.

Atmosphere
3 M KCl aqueous electrolyte
Geometry
three-electrode cell
Context
Binder-free Cu-CAT NWA electrode
Measurement source
p.3-4 · Supercapacitors Performance · Figure 3b,d
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu-CAT NWA specific capacitance at 0.5 A g-1Marked as a best value within this paper202 F g-1 at 0.5 A g-1Text
Exact Reported
p.3 · Supercapacitors Performance · Figure 3b,d
Cu-CAT NWA specific capacitance at 10 A g-1134 F g-1 at 10 A g-1Text
Exact Reported
p.3 · Supercapacitors Performance · Figure 3b,d
Cu-CAT NWA rate retention, 0.5 to 10 A g-1approximately 66%Text
Approximate
p.3 · Supercapacitors Performance · Figure 3d