Other — 2D conjugated metal-organic framework as a proton-electron dual conductor

Measurement evidence

Other

2D conjugated metal-organic framework as a proton-electron dual conductor · Choi J.Y., Stodolka M., Kim N. et al. · Chem · 2023 · 143-153

2 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Dye adsorption, solvent dispersion and PXRD stability tests

As-synthesised Zn-HHTP-H2O powder · Powder

MB+ and MO- aqueous dye adsorption for 12 h; dispersion in polar solvents; PXRD after boiling water and pH 4-13 treatments.

Temperature
293
Atmosphere
Aqueous/solvent treatments
Context
Pristine framework processability and stability context.
Measurement source
main p.5 / article p.146 · Results and discussion - Synthesis and characterizations of Zn-HHTP-H2O · Figures 2C-D; Figures S9-S10
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Methylene blue adsorption selectivityMB+ completely removed; MO- remained in solutionText
Qualitative
main p.4-p.5 / article p.145-p.146 · Results and discussion - Synthesis and characterizations of Zn-HHTP-H2O · Figure 2C-D
Dispersion in polar solventsWell dispersed in polar solvents without surfactantsText
Qualitative
main p.5 / article p.146 · Results and discussion - Synthesis and characterizations of Zn-HHTP-H2O · Figure S9
Chemical stability rangeRetained structural integrity after boiling water and pH 4-13 treatmentsText
Qualitative
main p.5 / article p.146 · Results and discussion - Synthesis and characterizations of Zn-HHTP-H2O · Figure S10

Dye adsorption, mass change after 95% RH exposure and volume-expansion imaging

Zn-HHTP-urea powder · Powder

MB+/MO- dye adsorption; pellet mass and dimensions before/after 95% RH exposure.

Atmosphere
95% RH for water uptake/volume expansion
Geometry
Pellets for weight and volume expansion.
Context
Urea-functionalised framework compared with pristine framework.
Measurement source
main p.8-p.9 / article p.149-p.150 · Results and discussion - Urea functionalization of Zn-HHTP-H2O · Figures S21-S22; Table S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Zn-HHTP-H2O weight percent H2O after 95% RH exposure10.06%SI Table
Exact Reported
SI p.18 · Weight change · Table S7
Weight percent H2O after 95% RH exposure14.20%SI Table
Exact Reported
SI p.18 · Weight change · Table S7