Complete recipeSource: Main
Route 1: Other
main p.5006 · Modified Synthesis of Cu[Ni(pdt)2]
Metal precursorsNa2[Ni(pdt)2] (0.630 g, 1.62 mmol); CuI (0.309 g, 1.62 mmol)
Linker precursorspdt2- already incorporated in Na2[Ni(pdt)2], prepared according to literature procedure.
SolventsAcetonitrile, 270 mL for Na2[Ni(pdt)2] solution and 75 mL for CuI solution.
AtmosphereDry N2 sparge for both flasks, then positive N2 during CuI addition; filtration in air.
TemperatureRoom temperature for precipitation; 90 C activation
Time0.5 h N2 sparge for each solution; overnight activation
Work-upCuI solution slowly added by syringe to Na2[Ni(pdt)2] solution causing rapid precipitation; solid filtered on 0.22 um nylon filter paper in air.
ActivationActivated overnight at 90 C under high vacuum on a Micromeritics ASAP 2420 with turbo pump.
Scalability contextReported isolated yield was 0.453 g, 69%, as a dark red microcrystalline powder.
Show 4 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Na2[Ni(pdt)2] | 0.630 g, 1.62 mmol | main p.5006 · Modified Synthesis of Cu[Ni(pdt)2] |
| Metal Source | CuI | 0.309 g, 1.62 mmol | main p.5006 · Modified Synthesis of Cu[Ni(pdt)2] |
| Solvent | acetonitrile | 270 mL plus 75 mL | main p.5006 · Modified Synthesis of Cu[Ni(pdt)2] |
| Other | dry N2 | sparged 30 min per flask; positive atmosphere during addition | main p.5006 · Modified Synthesis of Cu[Ni(pdt)2] |