Synthesis · Direct Evidence of Photoinduced Charge Transport Mechanism in 2D Conductive Metal Organic Frameworks

3 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

21051 · Synthesis of M-THQ MOFs

Metal precursorsCu(NO3)2.2.5H2O (532 mg, 2.29 mmol)

Linker precursorsTetrahydroxy-1,4-benzoquinone hydrate (THQ) (300 mg, 1.74 mmol)

SolventsDegassed H2O, 100 ml for THQ solution plus 100 ml for metal/ethylenediamine solution

AdditivesEthylenediamine (230 uL, 3.45 mmol)

AtmosphereDegassed water under N2 protection

Temperatureroom temperature reaction; drying at 80 deg C

Time12 h reaction; dried overnight

Work-upFiltered; washed with H2O (100 ml) twice and acetone (50 ml) twice; collected by centrifugation at 6000 rpm.

ActivationDried overnight in an oven at 80 deg C; no separate activation reported.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	tetrahydroxy-1,4-benzoquinone hydrate (THQ)	300 mg, 1.74 mmol	21051 · Synthesis of M-THQ MOFs
Metal Source	Cu(NO3)2.2.5H2O	532 mg, 2.29 mmol	21051 · Synthesis of M-THQ MOFs
Base	ethylenediamine	230 uL, 3.45 mmol	21051 · Synthesis of M-THQ MOFs
Solvent	degassed H2O	200 ml total	21051 · Synthesis of M-THQ MOFs

Partial recipeSource: Main

21051 · Synthesis of M-THQ MOFs

Metal precursorsHalf the Cu2+ amount (1.145 mmol Cu source) plus Zn(NO3)2.6H2O (1.145 mmol)

Linker precursorsTetrahydroxy-1,4-benzoquinone hydrate (THQ) as in Cu-THQ route

SolventsDegassed H2O

AdditivesEthylenediamine as in Cu-THQ route

AtmosphereDegassed water under N2 protection

Temperatureroom temperature reaction; drying at 80 deg C

Time12 h reaction; dried overnight

Work-upSame filtration, H2O/acetone washing, centrifugation and drying workflow as Cu-THQ route.

ActivationDried overnight in an oven at 80 deg C; no separate activation reported.

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	tetrahydroxy-1,4-benzoquinone hydrate (THQ)	300 mg, 1.74 mmol (inferred from parent route)	21051 · Synthesis of M-THQ MOFs
Metal Source	Cu(NO3)2.2.5H2O	1.145 mmol	21051 · Synthesis of M-THQ MOFs
Metal Source	Zn(NO3)2.6H2O	1.145 mmol	21051 · Synthesis of M-THQ MOFs
Base	ethylenediamine	230 uL, 3.45 mmol (inferred from parent route)	21051 · Synthesis of M-THQ MOFs
Solvent	degassed H2O	200 ml total (inferred from parent route)	21051 · Synthesis of M-THQ MOFs

Partial recipeSource: Main

21051 · Synthesis of M-THQ MOFs

Metal precursorsZn(NO3)2.6H2O (2.29 mmol)

Linker precursorsTetrahydroxy-1,4-benzoquinone hydrate (THQ) as in Cu-THQ route

SolventsDegassed H2O

AdditivesEthylenediamine as in Cu-THQ route

AtmosphereDegassed water under N2 protection

Temperatureroom temperature reaction; drying at 80 deg C

Time12 h reaction; dried overnight

Work-upSame filtration, H2O/acetone washing, centrifugation and drying workflow as Cu-THQ route.

ActivationDried overnight in an oven at 80 deg C; no separate activation reported.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	tetrahydroxy-1,4-benzoquinone hydrate (THQ)	300 mg, 1.74 mmol (inferred from parent route)	21051 · Synthesis of M-THQ MOFs
Metal Source	Zn(NO3)2.6H2O	2.29 mmol	21051 · Synthesis of M-THQ MOFs
Base	ethylenediamine	230 uL, 3.45 mmol (inferred from parent route)	21051 · Synthesis of M-THQ MOFs
Solvent	degassed H2O	200 ml total (inferred from parent route)	21051 · Synthesis of M-THQ MOFs