Spectroscopy — Copper-cobalt bimetallic conductive metal–organic frameworks as bifunctional oxygen electrocatalyst in alkaline and neutral media

3 measurement groups · 16 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

As-synthesised Cu3(HITP)2 powder · Powder

Thermo NEXSA G2 XPS; survey and high-resolution N 1s/Cu 2p/Cu LMM spectra in Figs. S5-S7.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu3(HITP)2 Cu LMM Cu+ feature	574.8 eV	—	—	Text Exact Reported	main p.3 · Material characterization · Fig. S7a
Cu3(HITP)2 Cu2+ Cu 2p binding energies	934.8 eV and 954.6 eV	—	—	Text Exact Reported	main p.3 · Material characterization · Fig. S6b
Cu3(HITP)2 Cu+ Cu 2p binding energies	932.9 eV and 952.7 eV	—	—	Text Exact Reported	main p.3 · Material characterization · Fig. S6b
Cu3(HITP)2 N 1s C-N peak	399.5 eV	—	—	Text Exact Reported	main p.3 · Material characterization · Fig. S6a
Cu3(HITP)2 N 1s Cu-Nx peak	398.2 eV	—	—	Text Exact Reported	main p.3 · Material characterization · Fig. S6a

As-synthesised CuCo-HITP powder · Powder

Fourier transform absorption spectrum on Nicolette IS10.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu3(HITP)2/CuCo-HITP FT-IR C=C benzene-ring vibration	around 1633 cm^-1	—	—	Text Approximate	main p.2 · Material characterization · Fig. 1c
Cu3(HITP)2/CuCo-HITP FT-IR N-H vibration	around 3442 cm^-1	—	—	Text Approximate	main p.2 · Material characterization · Fig. 1c

As-synthesised CuCo-HITP powder · Powder

Thermo NEXSA G2 XPS; high-resolution C 1s, N 1s, Cu 2p and Co 2p spectra in Fig. 3.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CuCo-HITP Cu LMM Cu2+ feature	569.1 eV	—	—	Visual Estimate Rounded Reported	SI rendered p.5 · Supporting Information · Figure S7b
CuCo-HITP Cu LMM Cu+ feature	572.5 eV	—	—	Visual Estimate Rounded Reported	SI rendered p.5 · Supporting Information · Figure S7b
CuCo-HITP C 1s C-C/C=C peak	284.8 eV	—	—	Text Exact Reported	main p.3 · Material characterization · Fig. 3a
CuCo-HITP Co2+ Co 2p binding energies	783.2 eV and 797.9 eV	—	—	Text Exact Reported	main p.3 · Material characterization · Fig. 3d
CuCo-HITP Co3+ Co 2p binding energies	780.9 eV and 796.2 eV	—	—	Text Exact Reported	main p.3 · Material characterization · Fig. 3d
CuCo-HITP Cu2+ 2p3/2 binding energy	934.6 eV	—	—	Text Exact Reported	main p.3 · Material characterization · Fig. 3c
CuCo-HITP Cu+ 2p3/2 binding energy	932.8 eV	—	—	Text Exact Reported	main p.3 · Material characterization · Fig. 3c
CuCo-HITP N 1s C-N peak	399.38 eV	—	—	Text Exact Reported	main p.3 · Material characterization · Fig. 3b
CuCo-HITP N 1s metal-Nx peak	397.88 eV	—	—	Text Exact Reported	main p.3 · Material characterization · Fig. 3b