cMOF Evidence Base
Electrochemistry Application — Electrically conductive [Fe4S4]-based organometallic polymers

Measurement evidence

Electrochemistry Application

Electrically conductive [Fe4S4]-based organometallic polymers · Kadota K., Chen T., Gormley E.L. et al. · Chemical Science · 2023 · 11410-11416

1 measurement group · 1 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Solid-state cyclic voltammetry

Voltammetry

[Fe4S4Cl2(Me-NHC)] (1) powder · Powder

5 uL DMF suspension (1.0 mg mL-1) drop-cast on CHI 104 3 mm glassy carbon electrode; 0.1 M LiPF6 or TBAPF6 in acetonitrile under N2; 10 mV s-1.

Temperature
298
Atmosphere
N2
Geometry
particle-coated glassy carbon working electrode, silver wire pseudo-reference, carbon cloth counter electrode
Context
pristine target polymer
Measurement source
S3 · Solid-state cyclic voltammetry (CV) · Fig. S13
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Irreversible reduction peak of 1 with LiPF6 electrolyteMarked as a best value within this paper-1.4 V vs FeCp2+/0——Text
Rounded Reported		4 · Electronic properties · Fig. S13