Berry T., Morey J.R., Arpino K.E. et al. · Inorganic Chemistry · 2022 · 6480-6487
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The article does not report porosity, electrochemical application, sensing, or thermoelectric measurements for these samples.
Caveat: Absence based on full read of the provided main-article text and rendered pages.
p001-p008 / 6480-6487 · Full article
Ni3(HIB)2 is assigned a highly disordered singlet ground state with a low-lying S = 1 excited state contributing to low-temperature heat capacity.
Caveat: The paper also notes a spin contribution such as spin-wave-like behaviour is possible.
p006 / 6485 · Results and Discussion · Figure 4a · Linked to 4 structured results
The MOFs combine localized magnetism with proximity to a metallic state in a kagome lattice.
Caveat: The transport measurements still show semiconducting gaps, not a true metallic ground state.
p006 / 6485 · Conclusion · Linked to 4 structured results
The apparent spin-liquid-like thermodynamic signatures are attributed mainly to stacking faults and structural disorder rather than intrinsic quantum spin liquid physics.
Caveat: The authors note disorder may mimic or enable QSL-type states; the attribution is interpretive and based on combined diffraction and thermodynamic evidence.
p006 / 6485 · Results and Discussion · Figure 5, Table 2 · Linked to 5 structured results
Ni3(HIB)2 and Cu3(HIB)2 are small-bandgap semiconductors rather than metallic-particle/insulating-matrix composites.
Caveat: Bulk pellet measurements can still include grain-boundary effects; authors argue field dependence indicates grain-boundary scattering is not dominating.
p004 / 6483 · Results and Discussion · Figure 3 · Linked to 6 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Cu3(hexaiminobenzene)2 | Cu3(HIB)2Cu2+ ions in a two-dimensional kagome lattice · hexaiminobenzene (HIB) anions | 2D · PristineLayered two-dimensional kagome metal-organic framework with rotational stacking faults and interlayer shifts. | p002 / 6481 · Introduction · Figure 1 |
| Ni3(hexaiminobenzene)2 | Ni3(HIB)2Ni2+ ions in a two-dimensional kagome lattice · hexaiminobenzene (HIB) anions | 2D · PristineLayered two-dimensional kagome metal-organic framework with rotational stacking faults and interlayer shifts. | p002 / 6481 · Introduction · Figure 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Cu3(HIB)2 densified pelletresearch_0185__mat__Cu3_HIB2 | Pellet · Target Sample · Pristine Framework | Powder specimen densified at >1000 bar and cut to an approximately rectangular pellet for physical-property measurements. | p003 / 6482 · Physical Property Measurement |
| Cu3(HIB)2 powderresearch_0185__mat__Cu3_HIB2 | Powder · Target Sample · Pristine Framework | Black precipitate isolated by centrifugation, washed and dried under vacuum. | p002 / 6481 · Experimental Section |
| Ni3(HIB)2 densified pelletresearch_0185__mat__Ni3_HIB2 | Pellet · Target Sample · Pristine Framework | Powder specimen densified at >1000 bar and cut to an approximately rectangular pellet for physical-property measurements. | p003 / 6482 · Physical Property Measurement |
| Ni3(HIB)2 powderresearch_0185__mat__Ni3_HIB2 | Powder · Target Sample · Pristine Framework | Black precipitate isolated by centrifugation, washed and dried under vacuum. | p002 / 6481 · Experimental Section |