Other — Structural, magnetic and electrical properties of one-dimensional tetraamidatodiruthenium compounds

6 measurement groups · 24 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Compound 1 single crystals and microcrystalline powder · Single Crystal

Quantum Design MPMSXL SQUID at 0.5 T over 2-300 K; diamagnetic corrections applied.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
zero-field splitting D	59.77 cm^-1	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3
g factor	2.0	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3
room-temperature effective magnetic moment	3.84 mu_B	—	—	Text Rounded Reported	p008-p009 · Synthesis characterisation
magnetic coupling zJ	-4.13 cm^-1	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3

Compound 2 crystalline solid / powder · Single Crystal

Quantum Design MPMSXL SQUID at 0.5 T over 2-300 K; diamagnetic corrections applied.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
zero-field splitting D	49.92 cm^-1	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3
g factor	2.06	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3
room-temperature effective magnetic moment	3.99 mu_B	—	—	Text Rounded Reported	p008-p009 · Synthesis characterisation
magnetic coupling zJ	-1.82 cm^-1	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3

Compound 3 crystalline solid / powder · Single Crystal

Quantum Design MPMSXL SQUID at 0.5 T over 2-300 K; diamagnetic corrections applied.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
zero-field splitting D	60.1 cm^-1	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3
g factor	2.01	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3
room-temperature effective magnetic moment	4.0 mu_B	—	—	Text Rounded Reported	p008-p009 · Synthesis characterisation
magnetic coupling zJ	-3.92 cm^-1	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3

Compound 4 single crystals and microcrystalline powder · Single Crystal

Quantum Design MPMSXL SQUID at 0.5 T over 2-300 K; diamagnetic corrections applied.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
zero-field splitting D	41.1 cm^-1	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3
g factor	2.24	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3
room-temperature effective magnetic moment	4.38 mu_B	—	—	Text Rounded Reported	p008-p009 · Synthesis characterisation
magnetic coupling zJ	-0.09 cm^-1	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3

Compound 5 crystalline solid / powder · Single Crystal

Quantum Design MPMSXL SQUID at 0.5 T over 2-300 K; diamagnetic corrections applied.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
zero-field splitting D	48.76 cm^-1	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3
g factor	2.29	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3
room-temperature effective magnetic moment	4.38 mu_B	—	—	Text Rounded Reported	p008-p009 · Synthesis characterisation
magnetic coupling zJ	-0.71 cm^-1	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3

Compound 6 crystalline solid / powder · Single Crystal

Quantum Design MPMSXL SQUID at 0.5 T over 2-300 K; diamagnetic corrections applied.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
zero-field splitting D	50.95 cm^-1	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3
g factor	2.07	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3
room-temperature effective magnetic moment	4.28 mu_B	—	—	Text Rounded Reported	p008-p009 · Synthesis characterisation
magnetic coupling zJ	0.0 cm^-1	—	—	Table Exact Reported	p006 · Magnetic properties · Table 3