cMOF Evidence Base
Porosity — Electroconductive porous coordination polymer Cu[Cu(pdt)2] composed of donor and acceptor building units

Measurement evidence

Porosity

Electroconductive porous coordination polymer Cu[Cu(pdt)2] composed of donor and acceptor building units · Takaishi S., Hosoda M., Kajiwara T. et al. · Inorganic Chemistry · 2009 · 9048-9050

1 measurement group · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Crystallographic pore/channel analysis from single-crystal structure

Single crystals of Cu[Cu(pdt)2] · Single Crystal

Pore dimensions and residual electron density inferred from X-ray crystal structure; no adsorption isotherm or BET surface area reported.

Temperature
100(2) for CIF; SI refinement at 100 K
Atmosphere
saturated CH3CN for SI pore electron-density refinement
Geometry
single crystal
Context
pristine Cu[Cu(pdt)2] framework
Measurement source
9049 / p002 · Crystal structure discussion · Figure 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Tentative CH3CN probability in pore refinementfixed to 1——Text
Exact Reported		p004 · Refinement of electronic density within channel · Figure S2
Tentative H2O refined probability in pore0.33——Text
Exact Reported		p004 · Refinement of electronic density within channel · Figure S2
One-dimensional vacant-space cross-sectionMarked as a best value within this paper3.4 A x 3.4 A——Text
Rounded Reported		9049 / p002 · Crystal structure discussion · Figure 2
Pore solvent mobility at 100 Ksolvent molecules are not fixed but moving even at 100 K——Text
Qualitative		p004 · Refinement of electronic density within channel · Figure S2