Partial recipeSource: Both
Route 1: Other
1 · Experimental Section - Synthesis
Metal precursorsCuBr.S(CH3)2; CuII(3,5-Dmpip-dtc)2
Linker precursors3,5-Dmpip-dtc supplied in CuII(3,5-Dmpip-dtc)2 precursor
Solvents10 ml acetonitrile, 10 ml acetone, 20 ml CHCl3; recrystallisation with hexane
Atmospherenot reported
Temperature40
Oxidant / reductantMixed CuI/CuII precursors; no separate oxidant or reductant reported
Work-upStirred 5 min, filtered, then black single crystals obtained in a couple of days by recrystallisation with hexane at 40 deg C.
Activationnot reported
Scalability contextSingle-crystal recrystallisation route; no yield or scale-up data reported.
Show 7 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | CuBr.S(CH3)2 | 0.041 g, 0.2 mmol · in 10 ml acetonitrile, diluted with 10 ml acetone | 1 · Experimental Section - Synthesis |
| Metal Source | CuII(3,5-Dmpip-dtc)2 | 0.041 g, 0.10 mmol · in 20 ml CHCl3 | 1 · Experimental Section - Synthesis |
| Linker | 3,5-Dmpip-dtc in CuII(3,5-Dmpip-dtc)2 | contained in 0.041 g, 0.10 mmol CuII(3,5-Dmpip-dtc)2 | 1 · Experimental Section - Synthesis |
| Solvent | acetonitrile | 10 ml | 1 · Experimental Section - Synthesis |
| Solvent | acetone | 10 ml | 1 · Experimental Section - Synthesis |
| Solvent | CHCl3 | 20 ml | 1 · Experimental Section - Synthesis |
| Solvent | hexane | used for recrystallisation | 1 · Experimental Section - Synthesis |