Electrical Transport — Two 3D supramolecular polymers constructed from an amino acid and a high-nuclear Ln6Cu24 cluster node

2 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

ground-crystal pellet of complex 2 · Pellet

Cylindrical pellet 0.2 cm thick and 0.3 cm diameter; frequency range 20 Hz to 1 MHz; temperature monitored with Pt-Rh thermocouple close to sample.

Temperature: 273.15-310
Atmosphere: Not specified
Geometry: Two-side silver paint contacts on cylindrical pellet
Context: pristine_framework
Measurement source: 3967-3968 · Electrical conductivity and magnetic properties; Experimental Section - Conductivity measurements · Figure 9b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electrical conductivity at 273.15 K	4.27 x 10^-7 S cm^-1 at 273.15 K	0.0000427 S m^-1	—	Text Exact Reported	3967 · Electrical conductivity and magnetic properties · Figure 9b
electrical conductivity at 310 KMarked as a best value within this paper	about 6.84 x 10^-6 S cm^-1 at 310 K	0.000684 S m^-1	—	Text Approximate	3967 · Electrical conductivity and magnetic properties · Figure 9b
semiconducting temperature dependence	conductivity increases with temperature; both polymers behave as semiconductors	—	—	Qualitative Qualitative	3963, 3967 · Abstract; Electrical conductivity and magnetic properties · Figure 9b

ground-crystal pellet of complex 1 · Pellet

Cylindrical pellet 0.2 cm thick and 0.3 cm diameter; frequency range 20 Hz to 1 MHz; temperature monitored with Pt-Rh thermocouple close to sample.

Temperature: 263.15-318.15
Atmosphere: Not specified
Geometry: Two-side silver paint contacts on cylindrical pellet
Context: pristine_framework
Measurement source: 3967-3968 · Electrical conductivity and magnetic properties; Experimental Section - Conductivity measurements · Figure 9a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electrical conductivity at 263.15 K	1.72 x 10^-4 S cm^-1 at 263.15 K	0.0172 S m^-1	—	Text Exact Reported	3967 · Electrical conductivity and magnetic properties · Figure 9a
electrical conductivity at 318.15 KMarked as a best value within this paper	2.57 x 10^-3 S cm^-1 at 318.15 K	0.257 S m^-1	—	Text Exact Reported	3967 · Electrical conductivity and magnetic properties · Figure 9a
semiconducting temperature dependence	conductivity increases with temperature; 1 is a semiconductor	—	—	Qualitative Qualitative	3967 · Electrical conductivity and magnetic properties · Figure 9a