Spectroscopy — Computational exploration of newly synthesized zirconium metal-organic frameworks UiO-66, -67, -68 and analogues

Measurement evidence

Spectroscopy

Computational exploration of newly synthesized zirconium metal-organic frameworks UiO-66, -67, -68 and analogues · Yang L.-M., Ganz E., Svelle S. et al. · Journal of Materials Chemistry C · 2014 · 7111-7125

1 measurement group · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CASTEP linear optical property calculation with scissor correction

Zr-UiO-66 hydroxylated perfect-crystal model · Model

Optical spectra shifted by scissor operator based on experimental Zr-UiO-66 band gap of 4.07 eV.

Atmosphere
not applicable
Context
model_system
Measurement source
7122-7123 · III.F · Fig. 7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Absorption band energy range4.07 to 50 eVText
Range
7123 · III.F · Fig. 7f
Static real dielectric function epsilon1(0)epsilon1(0) = 2.2Text
Rounded Reported
7122 · III.F · Fig. 7a
Maximum absorption coefficient relative to ZrO2only 30% of corresponding oxide ZrO20.3 fraction of ZrO2Text
Rounded Reported
7124 · IV
Real optical conductivity major peak energies5.3, 6.7, 8.9, 15.2, and 33.7 eVText
Rounded Reported
7122 · III.F · Fig. 7d
Reflectivity relative to ZrO2only 10% of corresponding oxide ZrO20.1 fraction of ZrO2Text
Rounded Reported
7124 · IV
Reflectivity R(0)R(0) = 0.039Text
Exact Reported
7122 · III.F · Fig. 7b
Refractive index at infinite wavelength n(0)n(0) = 1.5Text
Rounded Reported
7122 · III.F · Fig. 7a