Hou S., Xu X., Wang M. et al. · Journal of Materials Chemistry A · 2017 · 19054-19061
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The NP-150//AC hybrid supercapacitor combines high energy density with strong cycling stability, indicating application potential for energy storage.
Caveat: Device construction details such as active-mass loading and separator are incomplete, limiting direct reproducibility and benchmarking.
p007 / journal page 19060 · Results and discussion · Fig. 6, Table 1 · Linked to 3 structured results
SI Table S1 reports the NP-250 Ni0+ Ni 2p3/2 binding energy as 582.99 eV, which is inconsistent with the Ni 2p3/2 region and neighbouring sample values; the value was retained as reported and marked uncertain.
Caveat: Could be source typo or OCR/table extraction issue; no correction document was supplied.
p004 / SI page S-4 · Table S1 · Table S1 · Linked to 1 structured result
NP-150 gives the best capacitance because it balances hollow morphology, metallic Ni charge-transfer pathways and a conductive carbon skeleton.
Caveat: The relative contributions of Ni2P, metallic Ni and carbon are argued from comparative samples rather than independently deconvoluted.
p006 / journal page 19059 · Results and discussion · Fig. 4d · Linked to 4 structured results
Hollow Ni2P/Ni/C spheres form because PH3 generated from NaH2PO2 phosphorises Ni-MOFs while faster outward Ni diffusion than inward PH3 diffusion creates voids through the Kirkendall effect.
Caveat: Mechanism is inferred from morphology, phase evolution and cited Kirkendall literature rather than direct in situ measurement.
p003 / journal page 19056 · Results and discussion · Fig. 1 · Linked to 2 structured results
Metallic Ni in NP-50 and NP-150 lowers charge-transfer resistance relative to more highly phosphorised NP-250 and NP-350, improving charge transfer/electrical conductivity.
Caveat: No direct four-probe electronic conductivity was reported; inference is based on EIS Rct and XPS/XRD phase evidence.
p005 / journal page 19058 · Results and discussion · Fig. 4a · Linked to 5 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| N-0 annealed Ni-MOF-derived control | Ni/C; exact composition not fully specifiedmetallic Ni generated by annealing Ni-MOFs · carbonised MOF-derived carbon | 0D · DerivedAnnealed non-phosphorised control produced with 0 mg NaH2PO2.H2O; XRD shows metallic Ni peaks. | p002-p004 / journal pages 19055, 19057 · Experimental; Results and discussion · Fig. 3a |
| carbon-incorporated Janus-type Ni2P/Ni hollow spheres | Ni2P/Ni/CNi2P and metallic Ni nanocrystals derived from Ni-MOFs · porous carbon skeleton from carbonised MOF organic component | 0D · DerivedJanus-type Ni2P/Ni heterostructured hollow nanospheres incorporated with porous carbon. | p001-p003 / journal pages 19054-19056 · Abstract; Results and discussion · Fig. 1, Fig. 2 |
| Ni-based MOF nanospheres | Ni-BTC/PVP-derived Ni-MOF; exact framework formula not reportedNi2+ from Ni(NO3)2.6H2O · benzene-1,3,5-tricarboxylic acid (BTC); PVP additive/template used in synthesis | unknown · PristineCrystalline spherical Ni-MOF precursor; detailed formation mechanism referenced to previous work. | p002-p003 / journal pages 19055-19056 · Experimental; Results and discussion · Fig. 1, Fig. 2 |
| NP-150//AC hybrid supercapacitor device | NP-150 positive electrode // active carbon negative electrode in 2 M KOHNi2P/Ni/C positive electrode component · MOF-derived carbon in positive electrode; active carbon negative electrode | unknown · CompositeTwo-electrode hybrid supercapacitor device assembled from NP-150 and active carbon. | p006 / journal page 19059 · Results and discussion · Fig. 5 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| N-0research_0269__mat__mat_n0_annealed_control | Powder · Pristine Control · Derived Carbon | Ni-MOFs annealed at 450 deg C for 1 h in nitrogen with 0 mg NaH2PO2.H2O. | p002 / journal page 19055 · Synthesis of Ni2P/Ni/C hybrid composites |
| Ni-MOFsresearch_0269__mat__mat_ni_mof | Powder · Pristine Control · Pristine Framework | As-synthesised solvothermal Ni-MOF nanospheres, dried overnight at 60 deg C. | p002 / journal page 19055 · Synthesis of Ni-MOFs |
| NP-150research_0269__mat__mat_ni2p_ni_c | Powder · Target Sample · Composite | Ni-MOFs phosphorised/carbonised with 150 mg NaH2PO2.H2O at 450 deg C for 1 h in nitrogen. | p002-p006 / journal pages 19055-19059 · Experimental; Results and discussion · Fig. 2, Fig. 4 |
| NP-150//AC HSC deviceresearch_0269__mat__mat_np150_ac_device | Electrode · Composite Sample · Composite | Two-electrode HSC in 2 M KOH, with NP-150 positive electrode and active carbon negative electrode; m(NP-150)/m(AC) = 0.538. | p006 / journal page 19059 · Results and discussion · Fig. 5 |
| NP-150 working electroderesearch_0269__mat__mat_ni2p_ni_c | Electrode · Composite Sample · Composite | Slurry of NP-150, Super-P carbon black and PVDF in NMP at 80:10:10 coated on graphite and dried at 80 deg C for 24 h.graphite substrate | p002 / journal page 19055 · Electrochemical measurements |
| NP-250research_0269__mat__mat_ni2p_ni_c | Powder · Target Sample · Composite | Ni-MOFs phosphorised/carbonised with 250 mg NaH2PO2.H2O at 450 deg C for 1 h in nitrogen. | p002-p005 / journal pages 19055-19058 · Experimental; Results and discussion · Fig. 3, Fig. 4 |
| NP-350research_0269__mat__mat_ni2p_ni_c | Powder · Target Sample · Composite | Ni-MOFs phosphorised/carbonised with 350 mg NaH2PO2.H2O at 450 deg C for 1 h in nitrogen. | p002-p005 / journal pages 19055-19058 · Experimental; Results and discussion · Fig. 3, Fig. 4 |
| NP-50research_0269__mat__mat_ni2p_ni_c | Powder · Target Sample · Composite | Ni-MOFs phosphorised/carbonised with 50 mg NaH2PO2.H2O at 450 deg C for 1 h in nitrogen. | p002, p004 / journal pages 19055, 19057 · Experimental; Results and discussion · Fig. S1c |