cMOF Evidence Base

Synthesis evidence

Electrochemical reduction of carbon dioxide using a copper rubeanate metal organic framework

Hinogami R., Yotsuhashi S., Deguchi M. et al. · ECS Electrochemistry Letters · 2012

2 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Drop Cast

H17 · Experimental

Metal precursorspreformed CR-MOF particles
Linker precursorspreformed CR-MOF particles
Solventsisopropanol solution
Atmosphereair during drying, implied by air-dried
Temperaturenot stated
Timenot stated
Substrate orientationconductive carbon paper, Toray TGP-H-120, 0.36 mm thick, 18 mm square
Work-up100 mg CR-MOF dispersed in 3 mL isopropanol; 100 uL slurry dropped on carbon paper; air-dried; gripped in gold-plated electrode holder
Activationair-dried; no thermal activation reported
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
OtherCR-MOF particles100 mg used to prepare slurry; 100 uL slurry deposited · 100 mg in 3 mL isopropanolH17 · Experimental
Solventisopropanol solution3 mLH17 · Experimental
Otherconductive carbon paper (Toray Industries Inc., TGP-H-120)18 mm square, 0.36 mm thickH17 · Experimental
Partial recipeSource: Main

Route 2: Other

H17 · Experimental

Metal precursors50 mM CuSO4 5H2O aqueous solution
Linker precursors50 mM rubeanic acid ethanol solution
Solventsethanol; water
Atmospherenot stated
Temperaturenot stated
Timenot stated
Substrate orientationnot applicable
Work-upprecipitate washed with water and ethanol several times, separated by centrifuge, and air-dried
Activationair-dried; no separate activation reported
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Linkerrubeanic acid (Wako Pure Chemical Industries, Ltd.)50 mMH17 · Experimental
Metal SourceCuSO4 5H2O (Wako Pure Chemical Industries, Ltd.)50 mMH17 · Experimental
SolventethanolNot specifiedH17 · Experimental
SolventwaterNot specifiedH17 · Experimental