Xie X., Chen Y., Jing J. et al. · Journal of Alloys and Compounds · 2025 · 182131
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
All three c-MOF/[EMIM][BF4] planar supercapacitors operate over an 8 V window, substantially wider than typical reported supercapacitor windows.
Caveat: High-voltage testing was under controlled laboratory conditions; long-term high-voltage safety beyond reported tests is not established.
1.2 Electrochemical measurements · Fig. S17 · Linked to 3 structured results
The Mn-MOF planar supercapacitor has the highest areal capacitance, areal energy density and areal power density among the three c-MOF devices in SI Table S1.
Caveat: SI table units are preserved as printed; no independent recalculation was performed.
20 · Table S1 · Linked to 3 structured results
Screen-printing is positioned as scalable for flexible electrode manufacturing, but hydrothermal scale-up, ink rheology and post-processing consistency remain challenges.
Caveat: The paper discusses scale-up qualitatively rather than demonstrating industrial-scale batches.
3 · 2.5 Assembly of planar symmetric supercapacitors · Linked to 2 structured results
Series connection extends voltage and parallel connection increases current output for Mn-MOF printed supercapacitor packs.
Caveat: CV series testing was limited by the electrochemical workstation to 13 V; 16 V verification came from GCD for 2S-SP.
8 · 3.4 · Fig. 5 · Linked to 3 structured results
Mn-MOF retains nanorod morphology after cycling but capacitance retention decreases to 72.15% after 5000 cycles, with slight XRD intensity reduction.
Caveat: Cycling protocol details are limited in the text layer.
7 · 3.2 · Figs. S9-S11 · Linked to 1 structured result
The Co-, Ni- and Mn-HHTP products are conductive MOFs with isomorphous metal-catecholate structures.
Caveat: No CIF is supplied in the assigned documents; assignment relies on XRD/TEM/FT-IR/Raman/XPS and comparison to reported M-CAT literature.
3-4 · 3.1 · Fig. 2 · Linked to 4 structured results
Mn-MOF performs best because its smaller macrocycle diameter and hierarchical pore structure better match [EMIM][BF4] ion dimensions, improving ion transport and active-site utilisation.
Caveat: Ion-transport rates are from MD models; pore-size distribution is described qualitatively/approximately in SI.
7-8 · 3.2-3.3 · Fig. 3, Fig. 4 · Linked to 4 structured results
HHTP hydroxyl/quinone chemistry contributes reversible redox activity, raising pseudocapacitive contribution and helping broaden the operating potential window.
Caveat: Mechanistic interpretation is inferred from spectroscopy, CV shape and literature; direct in situ redox-state tracking is not reported.
5 · 3.2 · Fig. 3 · Linked to 5 structured results
Mn-MOF devices have the lowest charge-transfer resistance, facilitating faster internal Faradaic reactions.
Caveat: EIS values come from SI prose; equivalent-circuit fitting details are not provided in the extracted text.
7 · 3.2 · Fig. S12 · Linked to 3 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Co-MOF / Co3(HHTP)2 conductive metal-organic frameworkBrowse family: Co₃(HHTP)₂ / Co–HHTP | Co3(HHTP)2Co cations; Co2+ assigned by XPS · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineIsomorphous conductive metal-catecholate c-MOF with hexagonal planar macrocycles aligned along the c-axis and pi-pi corrugated stacking into honeycomb nanorods. | 3 · 3.1 Physical and chemical characteristics · Fig. 1a |
| [EMIM][BF4]/PVDF-HFP ionic liquid gel electrolyte | [EMIM][BF4] with PVDF-HFP | unknown · CompositeGel electrolyte made from PVDF-HFP and 1-ethyl-3-methylimidazolium tetrafluoroborate. | 2 · 2.3 Synthesis of ionic liquid electrolytes |
| Mn-MOF / Mn3(HHTP)2 conductive metal-organic frameworkBrowse family: Mn₃(HHTP)₂ family | Mn3(HHTP)2Mn cations; Mn2+ assigned by XPS · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineIsomorphous conductive metal-catecholate c-MOF with hexagonal planar macrocycles aligned along the c-axis and pi-pi corrugated stacking into honeycomb nanorods. | 7 · 3.2 Electrochemical performance tests · Fig. 3 |
| Ni-MOF / Ni3(HHTP)2 conductive metal-organic frameworkBrowse family: Ni₃(HHTP)₂ / Ni–HHTP | Ni3(HHTP)2Ni cations; Ni2+ assigned by XPS · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineIsomorphous conductive metal-catecholate c-MOF with hexagonal planar macrocycles aligned along the c-axis and pi-pi corrugated stacking into honeycomb nanorods. | 3 · 3.1 Physical and chemical characteristics · Fig. 1a |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Co/Ni/Mn-MOF molecular dynamics model systemsresearch_0293__mat__mn_mof | Model · Model System · Model | single unit cell and triple c-axis expanded MD model with [EMIM][BF4] ion pairs | 8 · 3.3 Molecular dynamics simulation · Fig. 4 |
| Co-MOF powderresearch_0293__mat__co_mof | Powder · Pristine Control · Pristine Framework | hydrothermal powder, washed and vacuum dried | 2 · 2.2 Synthesis of c-MOF products |
| Co-MOF planar symmetric supercapacitorresearch_0293__mat__co_mof | Electrode · Composite Sample · Composite | screen-printed serrated-interdigital all-solid-state planar supercapacitorTeslin paper | 3 · 2.5 Assembly of planar symmetric supercapacitors · Fig. 1b |
| [EMIM][BF4]/PVDF-HFP gel electrolyteresearch_0293__mat__emim_bf4_gel | Unknown · Composite Component · Composite | gel electrolyte precursor with [EMIM][BF4] added at PVDF-HFP:[EMIM][BF4] mass ratio 1:9 | 2 · 2.3 Synthesis of ionic liquid electrolytes |
| 2P-SP Mn-MOF supercapacitor packresearch_0293__mat__mn_mof | Electrode · Composite Sample · Composite | two Mn-MOF planar supercapacitors connected in parallelTeslin paper | 8 · 3.4 Applications · Fig. 5e |
| 2S-SP Mn-MOF supercapacitor packresearch_0293__mat__mn_mof | Electrode · Composite Sample · Composite | two Mn-MOF planar supercapacitors connected in seriesTeslin paper | 8 · 3.4 Applications · Fig. 5 |
| 5P-SP Mn-MOF supercapacitor packresearch_0293__mat__mn_mof | Electrode · Composite Sample · Composite | five Mn-MOF planar supercapacitors connected in parallelTeslin paper | 8 · 3.4 Applications · Fig. 5e |
| 5S-SP Mn-MOF supercapacitor packresearch_0293__mat__mn_mof | Electrode · Composite Sample · Composite | five Mn-MOF planar supercapacitors connected in seriesTeslin paper | 8 · 3.4 Applications · Fig. 5c |
| Mn-MOF powderresearch_0293__mat__mn_mof | Powder · Target Sample · Pristine Framework | hydrothermal powder, washed and vacuum dried | 2 · 2.2 Synthesis of c-MOF products |
| Mn-MOF planar symmetric supercapacitorresearch_0293__mat__mn_mof | Electrode · Target Sample · Composite | screen-printed serrated-interdigital all-solid-state planar supercapacitorTeslin paper | 5 · 3.2 Electrochemical performance tests · Fig. 1b |
| Ni-MOF powderresearch_0293__mat__ni_mof | Powder · Pristine Control · Pristine Framework | hydrothermal powder, washed and vacuum dried | 2 · 2.2 Synthesis of c-MOF products |
| Ni-MOF planar symmetric supercapacitorresearch_0293__mat__ni_mof | Electrode · Composite Sample · Composite | screen-printed serrated-interdigital all-solid-state planar supercapacitorTeslin paper | 3 · 2.5 Assembly of planar symmetric supercapacitors · Fig. 1b |