Spectroscopy — Copper-doped strontium metal-organic framework: Dual-function active material for supercapacitor and oxygen evolution reaction

Measurement evidence

Spectroscopy

Copper-doped strontium metal-organic framework: Dual-function active material for supercapacitor and oxygen evolution reaction · Mahmud A.A., Alshatteri A.H., Alhasan H.S. et al. · Electrochimica Acta · 2024 · 144857

3 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

FT-IR spectroscopy

Cu-doped Sr MOF powder · Powder

PerkinElmer Spectrum 100; 600-2100 cm-1 range for BTC, undoped Sr MOF and Cu-doped Sr MOF.

Context
comparison of linker, pristine Sr MOF and Cu-doped Sr MOF
Measurement source
2 · 2.3 Material characterizations · Fig. 2b
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu-O coordination peak722 cm-1Text
Rounded Reported
6 · 3.1 Materials characterization · Fig. 2b
Sr-O FTIR peak range in Sr MOF700-765 cm-1range 700-765 cm-1Text
Range
6 · 3.1 Materials characterization · Fig. 2b

Raman spectroscopy

Cu-doped Sr MOF powder · Powder

Renishaw inVia confocal Raman microscope with 532 nm laser; undoped and Cu-doped Sr MOF compared.

Context
doped MOF powder compared with undoped Sr MOF
Measurement source
2 · 2.3 Material characterizations · Fig. 4a
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Raman Sr-O and BTC-related peaksreported Raman peak assignments for Sr-O and BTC ligand modesText
Qualitative
6 · 3.1 Materials characterization · Fig. 4a

X-ray photoelectron spectroscopy (XPS)

Cu-doped Sr MOF powder · Powder

PHI 5000 Versa Probe II with Al-Kalpha source; Sr 3d, O 1s, C 1s and Cu 2p analysed.

Context
doped MOF powder compared with undoped Sr MOF
Measurement source
2 · 2.3 Material characterizations · Fig. 3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu(I) 2p3/2 binding energy932.5 eVText
Exact Reported
6 · 3.1 Materials characterization · Fig. 3d
Cu(II) 2p3/2 binding energy934.1 eVText
Exact Reported
6 · 3.1 Materials characterization · Fig. 3d
Cu valence assignmentmixed-valence Cu with Cu(II) and partial Cu(I)Text
Qualitative
6 · 3.1 Materials characterization · Fig. 3d
C-O-Cu O 1s binding energy533.1 eVText
Exact Reported
6 · 3.1 Materials characterization · Fig. 3b