Other — Control of crystalline proton-conducting pathways by water-induced transformations of hydrogen-bonding networks in a metal-organic framework

Measurement evidence

Other

Control of crystalline proton-conducting pathways by water-induced transformations of hydrogen-bonding networks in a metal-organic framework · Sadakiyo M., Yamada T., Honda K. et al. · Journal of the American Chemical Society · 2014 · 7701-7707

1 measurement group · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

thermogravimetric analysis with Bruker TG-DTA 2000SA

Calorimetry and thermal analysis Thermogravimetric analysis

air-dried 1·2H2O sample · Powder

air-dried 1·nH2O under nitrogen gas flow of 100 mL min-1, room temperature to 500 °C, 5 °C min-1 heating rate

Atmosphere: nitrogen gas flow, 100 mL min-1
Geometry: powder
Context: pristine hydrated MOF phase
Measurement source: 7702-7703 · Physical Measurements; Structural Analysis · Figure 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
framework thermal stability limit	oxalate-bridged 2-D framework including adipic acid is stable below 200 °C	—	below	Text Approximate	7703 · Structural Analysis · Figure 2
TGA water desorption temperature	clear weight loss around 60 °C attributed to desorption of two water molecules per formula	—	around	Text Approximate	7703 · Structural Analysis · Figure 2