Measurement evidence
Ni(II)-Based Coordination Polymer with Pi-Conjugated Organic Linker as Catalyst for Oxygen Evolution Reaction Activity · Kumar T., Karmakar A., Halder A. et al. · Energy and Fuels · 2022 · 2722-2730
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
as-synthesised CP 1 blue needle-shaped crystals · Single Crystal
KBr pellet; PerkinElmer Spectrum Two.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| asymmetric carboxylate stretching band | 1552 cm-1 | — | — | Text Exact Reported | 2724 · Results and Discussion · Figure S1B |
| O-H stretching band | 3375 cm-1 | — | — | Text Exact Reported | 2724 · Results and Discussion · Figure S1B |
CP 1 catalyst ink drop-cast on glassy carbon electrode · Electrode
High-resolution Ni 2p3/2 XPS of CP 1 before and after OER analysis.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| post-OER Ni3+ binding energy | 857.3 eV | — | — | Text Exact Reported | 2726 · 3.1 Electrocatalytic Water Oxidation · Figure 5C |
as-synthesised CP 1 blue needle-shaped crystals · Single Crystal
NEXSA Surface Analysis; Al-Kalpha 1486.6 eV; 400 um spot; Avantage deconvolution.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Ni 2p1/2 binding energy | 873.1 eV | — | — | Text Exact Reported | 2724 · Results and Discussion · Figure 3B |
| Ni 2p3/2 binding energy | 855.5 eV | — | — | Text Exact Reported | 2724 · Results and Discussion · Figure 3B |
as-synthesised CP 2 blue crystals · Single Crystal
KBr pellet; PerkinElmer Spectrum Two.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| O-H stretching band | 3355 cm-1 | — | — | Text Exact Reported | 2723 · 2.3 Synthesis of CP 2 · Figure S1B |
as-synthesised CP 2 blue crystals · Single Crystal
NEXSA Surface Analysis; Al-Kalpha 1486.6 eV; 400 um spot; Avantage deconvolution.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Ni oxidation state before OER | Ni species in +2 form in both CPs 1 and 2 | — | — | Text Qualitative | 2724 · Results and Discussion · Figure 3B |