Computational Modelling — High Proton Mobility with High Directionality in Isolated Channels of MOF-74

Measurement evidence

Computational Modelling

High Proton Mobility with High Directionality in Isolated Channels of MOF-74 · Hwang S., Lee E.J., Song D. et al. · ACS Applied Materials and Interfaces · 2018 · 35354-35660

1 measurement group · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Simple geometric modelling based on MOF-74 crystal structure and water-water hydrogen-bond O-O distance

geometric model of pore-filling H2O in Co-MOF-74 channels · Model

Modelled feasibility of a continuous chain of non-coordinated H2O molecules within Co-MOF-74 channels; hydrogen atoms omitted for clarity.

Atmosphere
not applicable
Geometry
2D views along c-axis (001) and a-axis (100)
Context
model of water-containing Co-MOF-74 channels
Measurement source
S-13 · Section S9 · Figures S8-S9
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
geometric feasibility of continuous water chainSimple geometric modelling supports formation of a continuous chain of non-coordinated H2O molecules within Co-MOF-74 channels.Text
Qualitative
S-13 · Section S9 · Figures S8-S9
O-O distance used for H2O hydrogen-bond geometric model2.8 +/- 0.1 A2.8 angstrom+/- 0.1 AText
Exact Reported
S-13 · Section S9 · Figures S8-S9