Measurement evidence
Redox-Active Two-Dimensional Tetrathiafulvalene-Copper Metal-Organic Framework with Boosted Electrochemical Performances for Supercapatteries · Zhang Z.-R., Ren Z.-H., Luo C.-Y. et al. · Inorganic Chemistry · 2023 · 4672-4679
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Iodine-treated crystals of 1 (1-ox) · Single Crystal
PXRD comparison of simulated 1 and experimental 1, 1-ox' and 1-ox patterns.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| framework crystallinity after iodine treatment | PXRD peaks of 1-ox and 1-ox' become wider/weaker and shift slightly, but most peaks remain; framework maintains crystalline and structural integrity. | — | — | Text Qualitative | p003 / 4674 · 2.2. Characterizations · Figure 2b |
Maroon single crystals of 1 · Single Crystal
Crystal data collected on Bruker APEX-II CCD at 120 K; SHELXS/SHELXL refinement.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| unit-cell a | 9.6255(5) A | — | (5) | SI Table Exact Reported | p019 / SI · 3. Table · Table S1 |
| unit-cell b | 9.6561(5) A | — | (5) | SI Table Exact Reported | p019 / SI · 3. Table · Table S1 |
| unit-cell c | 16.1533(8) A | — | (8) | SI Table Exact Reported | p019 / SI · 3. Table · Table S1 |
| central TTF C=C bond length | 1.347(5) A | — | (5) | Text Exact Reported | p002 / 4673 · 2.1. Synthesis and Crystal Structures · Figure 1 |
| R1 for observed reflections | R1 [I>2sigma(I)] = 0.0394 | — | — | SI Table Exact Reported | p019 / SI · 3. Table · Table S1 |
| space group | P-1 | — | — | SI Table Exact Reported | p019 / SI · 3. Table · Table S1 |
| unit-cell volume | 1384.85(12) A^3 | — | (12) | SI Table Exact Reported | p019 / SI · 3. Table · Table S1 |