Synthesis evidence

Synthesis, identification and application of metal organic framework for removal of industrial cationic dyes

Kiwaan H.A., Sh. Mohamed F., El-Bindary A.A. et al. · Journal of Molecular Liquids · 2021 · 117435

1 structured synthesis route

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Main

Route 1: Hydrothermal

2 · 2.3. Preparation of the adsorbent

Metal precursors1.19 g zinc nitrate hexahydrate
Linker precursors0.473 g benzimidazole
Solvents90 mL DMF; methanol workup
Atmospheresealed Teflon autoclave; atmosphere not otherwise specified
Temperature130
Time24
Work-upSolid soaked in methanol for 24 h at room temperature to remove DMF/unreacted chemicals; methanol decanted; crystals dried at room temperature for 24 h.
ActivationDried for another 24 h under vacuum at 160 C.
Scalability context150 mL Teflon autoclave batch synthesis.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcezinc nitrate hexahydrate1.19 g2 · 2.3. Preparation of the adsorbent
Linkerbenzimidazole0.473 g2 · 2.3. Preparation of the adsorbent
SolventDMF90 mL2 · 2.3. Preparation of the adsorbent
Solventmethanolsoaked for 24 h2 · 2.3. Preparation of the adsorbent