Electrical Transport — Interdigitated conducting tetrathiafulvalene-based coordination networks

Measurement evidence

Electrical Transport

Interdigitated conducting tetrathiafulvalene-based coordination networks · Bechu D., Xie L.S., Le Breton N. et al. · Chemical Communications · 2020 · 2407-2410

9 measurement groups · 15 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

two-probe pressed-pellet conductivity

Network 4 as-synthesised pressed pellet · Pellet

Two-probe conductivity; Keithley 2450 sourcemeter; ambient 296 K; voltage swept from -0.5 to +0.5 V. Native/as-synthesised network 4 pressed pellet.

Temperature
296
Atmosphere
ambient
Geometry
pressed pellet, approximately 200 MPa
Context
native framework transport control
Measurement source
p009 · Conductivity measurements
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
room-temperature conductivity, as-synthesised pressed pellet<10^-13 S cm^-1Text
Range
p003 / journal p2409 · Conductivity discussion

two-probe single-crystal conductivity

Network 4 as-synthesised single crystal · Single Crystal

Two-probe conductivity; Keithley 2450 sourcemeter; ambient 296 K; voltage swept from -0.5 to +0.5 V. Native/as-synthesised network 4.

Temperature
296
Atmosphere
ambient
Geometry
single crystal contacted with gold wires dipped in carbon paste; b/c axis devices reported
Context
native framework transport control
Measurement source
p009 · Conductivity measurements
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
room-temperature conductivity, as-synthesised single crystal<10^-13 S cm^-1Text
Range
p003 / journal p2409 · Conductivity discussion

two-probe pressed-pellet conductivity

Network 4 iodine-treated pressed pellet · Pellet

Two-probe conductivity; Keithley 2450 sourcemeter; ambient 296 K; voltage swept from -0.5 to +0.5 V. Iodine-treated network 4 pressed-pellet devices.

Temperature
296
Atmosphere
ambient
Geometry
pressed pellet, approximately 200 MPa
Context
iodine-treated framework
Measurement source
p010 · Conductivity measurements · Figure ESI 12
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
average pellet conductivity after iodine treatmentMarked as a best value within this paperAverage = 1.1 x 10^-5 S/cmFigure Axis
Rounded Reported
p010 · Figure ESI 12 · Figure ESI 12

two-probe single-crystal conductivity

Network 4 iodine-treated single crystal · Single Crystal

Two-probe conductivity; Keithley 2450 sourcemeter; ambient 296 K; voltage swept from -0.5 to +0.5 V. Iodine-treated network 4 measured along b axis.

Temperature
296
Atmosphere
ambient
Geometry
single crystal, b crystallographic axis
Context
iodine-treated framework
Measurement source
p009 · Conductivity measurements · Figure ESI 10
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
conductivity, oxidised 4 b-axis device 1Device 1: 1 x 10^-7 S/cmFigure Axis
Rounded Reported
p009 · Figure ESI 10 · Figure ESI 10
conductivity, oxidised 4 b-axis device 2Device 2: 2 x 10^-7 S/cmFigure Axis
Rounded Reported
p009 · Figure ESI 10 · Figure ESI 10

two-probe single-crystal conductivity

Network 4 iodine-treated single crystal · Single Crystal

Two-probe conductivity; Keithley 2450 sourcemeter; ambient 296 K; voltage swept from -0.5 to +0.5 V. Iodine-treated network 4 measured along c axis.

Temperature
296
Atmosphere
ambient
Geometry
single crystal, c crystallographic axis
Context
iodine-treated framework
Measurement source
p009 · Conductivity measurements · Figure ESI 10
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
conductivity, oxidised 4 c-axis device 1Marked as a best value within this paperDevice 1: 1 x 10^-6 S/cmFigure Axis
Rounded Reported
p009 · Figure ESI 10 · Figure ESI 10
conductivity, oxidised 4 c-axis device 2Device 2: 7 x 10^-7 S/cmFigure Axis
Rounded Reported
p009 · Figure ESI 10 · Figure ESI 10
conductivity enhancement after iodine treatmentsix orders of magnitude (10^-6 vs. 10^-12 S cm^-1)Text
Approximate
p001 / journal p2407 · Abstract
main-text single-crystal conductivity range after iodine exposure10^-6-10^-7 S cm^-1Text
Range
p003 / journal p2409 · Conductivity discussion

two-probe pressed-pellet conductivity

Network 5 as-synthesised pressed pellet · Pellet

Two-probe conductivity; Keithley 2450 sourcemeter; ambient 296 K; voltage swept from -0.5 to +0.5 V. Native/as-synthesised network 5 pressed pellet.

Temperature
296
Atmosphere
ambient
Geometry
pressed pellet, approximately 200 MPa
Context
native framework transport control
Measurement source
p009 · Conductivity measurements
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
room-temperature conductivity, as-synthesised pressed pellet<10^-13 S cm^-1Text
Range
p003 / journal p2409 · Conductivity discussion

two-probe single-crystal conductivity

Network 5 as-synthesised single crystal · Single Crystal

Two-probe conductivity; Keithley 2450 sourcemeter; ambient 296 K; voltage swept from -0.5 to +0.5 V. Native/as-synthesised network 5.

Temperature
296
Atmosphere
ambient
Geometry
single crystal contacted with gold wires dipped in carbon paste; b/c axis devices reported
Context
native framework transport control
Measurement source
p009 · Conductivity measurements
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
room-temperature conductivity, as-synthesised single crystal<10^-13 S cm^-1Text
Range
p003 / journal p2409 · Conductivity discussion

two-probe single-crystal conductivity

Network 5 iodine-treated single crystal · Single Crystal

Two-probe conductivity; Keithley 2450 sourcemeter; ambient 296 K; voltage swept from -0.5 to +0.5 V. Iodine-treated network 5 measured along b axis.

Temperature
296
Atmosphere
ambient
Geometry
single crystal, b crystallographic axis
Context
iodine-treated framework
Measurement source
p010 · Conductivity measurements · Figure ESI 11
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
conductivity, oxidised 5 b-axis device 1Device 1: 3 x 10^-7 S/cmFigure Axis
Rounded Reported
p010 · Figure ESI 11 · Figure ESI 11
conductivity, oxidised 5 b-axis device 2Device 2: 8 x 10^-8 S/cmFigure Axis
Rounded Reported
p010 · Figure ESI 11 · Figure ESI 11

two-probe single-crystal conductivity

Network 5 iodine-treated single crystal · Single Crystal

Two-probe conductivity; Keithley 2450 sourcemeter; ambient 296 K; voltage swept from -0.5 to +0.5 V. Iodine-treated network 5 measured along c axis.

Temperature
296
Atmosphere
ambient
Geometry
single crystal, c crystallographic axis
Context
iodine-treated framework
Measurement source
p010 · Conductivity measurements · Figure ESI 11
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
conductivity, oxidised 5 c-axis device 1Device 1: 2 x 10^-7 S/cmFigure Axis
Rounded Reported
p010 · Figure ESI 11 · Figure ESI 11
conductivity, oxidised 5 c-axis device 2Marked as a best value within this paperDevice 2: 1 x 10^-6 S/cmFigure Axis
Rounded Reported
p010 · Figure ESI 11 · Figure ESI 11