Measurement evidence
A Computation-Guided Design of Highly Defined and Dense Bimetallic Active Sites on a Two-Dimensional Conductive Metal–Organic Framework for Efficient H2O2 Electrosynthesis · Li Z., Jia J., Sang Z. et al. · Angewandte Chemie - International Edition · 2024 · e202408500
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Ni-TCPP(Co)/CNT/Nafion RRDE catalyst layer · Electrode
O2-saturated 0.1 M KOH; potential stepwise 1 to 0 V vs RHE; 60 s
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| ATR-SEIRAS *OOH site assignment | *OOH peaks assigned to both Ni-OOH and Co-OOH; HOOH signals detected | — | — | Qualitative Qualitative | 6 · Catalytic Performance · Figure S20 |
Ni-TCPP(Co) nanosheets/crystals · Nanosheet
coordination and oxidation-state analysis of Co and Ni sites
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Co-N coordination number | N = 4 | — | — | SI Table Exact Reported | S37 · Supplementary Tables · Table S3 |
| Co-N distance | 1.95 A | — | R +/- 1% | SI Table Exact Reported | S37 · Supplementary Tables · Table S3 |
| Ni-O coordination number | N = 4 | — | — | SI Table Exact Reported | S37 · Supplementary Tables · Table S3 |
| Ni-O distance | 2.06 A | — | R +/- 1% | SI Table Exact Reported | S37 · Supplementary Tables · Table S3 |
| Co WT-EXAFS intensity maximum | ~4.2 A-1 | — | — | Text Approximate | S20 · Figure S15 discussion · Figure S15 |
| Ni WT-EXAFS intensity maximum | ~3.8 A-1 | — | — | Text Approximate | S21 · Figure S16 discussion · Figure S16 |
Ni-TCPP(Co) nanosheets/crystals · Nanosheet
N 1s, O 1s, Ni 2p, Co 2p, FTIR coordination assignments
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| FTIR coordination evidence | Absence of O-H near 3425 cm-1 and porphyrin N-H near 966 cm-1 indicates M-N and M-O coordination | — | — | Qualitative Qualitative | S19 · Figure S14 discussion · Figure S14 |
| O 1s C=O binding energy | 532.1 eV | — | — | Text Exact Reported | 4 · Morphological and Structural Characterization · Figure 2d,e; Figure S12 |
| N 1s C-N binding energy | 400.7 eV | — | — | Text Exact Reported | 4 · Morphological and Structural Characterization · Figure 2d,e; Figure S12 |
| N 1s C=N binding energy | 399.84 eV | — | — | Text Exact Reported | 4 · Morphological and Structural Characterization · Figure 2d,e; Figure S12 |
| O 1s C-O binding energy | 533.35 eV | — | — | Text Exact Reported | 4 · Morphological and Structural Characterization · Figure 2d,e; Figure S12 |
| N 1s Co-N binding energy | 398.6 eV | — | — | Text Exact Reported | 4 · Morphological and Structural Characterization · Figure 2d,e; Figure S12 |
| Ni 2p1/2 binding energy | 874.0 eV | — | — | Text Exact Reported | 4 · Morphological and Structural Characterization · Figure 2d,e; Figure S12 |
| Ni 2p3/2 binding energy | 856.2 eV | — | — | Text Exact Reported | 4 · Morphological and Structural Characterization · Figure 2d,e; Figure S12 |
| O 1s Ni-O binding energy | 531.35 eV | — | — | Text Exact Reported | 4 · Morphological and Structural Characterization · Figure 2d,e; Figure S12 |