Electrochemistry Application — Facet Engineering in Ultrathin Two-Dimensional NiFe Metal-Organic Frameworks by Coordination Modulation for Enhanced Electrocatalytic Water Oxidation

Measurement evidence

Electrochemistry Application

Facet Engineering in Ultrathin Two-Dimensional NiFe Metal-Organic Frameworks by Coordination Modulation for Enhanced Electrocatalytic Water Oxidation · Zhao H., Yu L., Zhang L. et al. · ACS Sustainable Chemistry and Engineering · 2021 · 10892-10901

8 measurement groups · 17 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

cyclic voltammetry double-layer capacitance

NiFe-MOF NSs catalyst ink on glassy carbon · Electrode

Non-Faradaic CV at 10, 20, 30, 40 and 50 mV s^-1; potential range 0.096-0.196 V vs Hg/HgO; Cdl = Ic/v

Atmosphere
1 M KOH
Geometry
glassy carbon disk electrode
Context
MOF/carbon black/Nafion catalyst ink
Measurement source
10893 · Electrochemical Measurements · Figure 4a,b
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
NiFe-MOF bulk double-layer capacitance0.477 mF cm-2Figure Axis
Rounded Reported
10897 · Results and Discussion · Figure 4b
Fe-MOF double-layer capacitance0.262 mF cm-2Figure Axis
Rounded Reported
10897 · Results and Discussion · Figure 4b
Ni-MOF NS double-layer capacitance0.116 mF cm-2Figure Axis
Rounded Reported
10897 · Results and Discussion · Figure 4b
NiFe-MOF NS double-layer capacitanceMarked as a best value within this paper0.526 mF cm-2Text
Exact Reported
10897 · Results and Discussion · Figure 4b

linear sweep voltammetry OER testing

NiFe-MOF bulk catalyst ink on glassy carbon · Electrode

O2-saturated 1 M KOH, three-electrode cell, LSV 5 mV s^-1, iR-corrected

Temperature
room temperature
Atmosphere
O2-saturated electrolyte
Geometry
5 mm glassy carbon disk
Context
MOF/carbon black/Nafion catalyst ink
Measurement source
10896 · Results and Discussion · Figure 3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
current density at 1.55 V vs RHE9.57 mA cm-2 at 1.55 V vs RHEText
Exact Reported
10897 · Results and Discussion · Figure 3b
Tafel slope82.23 mV dec-1Text
Exact Reported
10897 · Results and Discussion · Figure 3c

linear sweep voltammetry OER testing

Fe-MOF catalyst ink on glassy carbon · Electrode

O2-saturated 1 M KOH, three-electrode cell, LSV 5 mV s^-1, iR-corrected

Temperature
room temperature
Atmosphere
O2-saturated electrolyte
Geometry
5 mm glassy carbon disk
Context
MOF/carbon black/Nafion catalyst ink
Measurement source
10896 · Results and Discussion · Figure 3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Tafel slope166.94 mV dec-1Figure Axis
Rounded Reported
10896 · Results and Discussion · Figure 3c

linear sweep voltammetry OER testing

Ni-MOF NSs catalyst ink on glassy carbon · Electrode

O2-saturated 1 M KOH, three-electrode cell, LSV 5 mV s^-1, iR-corrected

Temperature
room temperature
Atmosphere
O2-saturated electrolyte
Geometry
5 mm glassy carbon disk
Context
MOF/carbon black/Nafion catalyst ink
Measurement source
10896 · Results and Discussion · Figure 3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
current density at 1.55 V vs RHE7.24 mA cm-2 at 1.55 V vs RHEText
Exact Reported
10897 · Results and Discussion · Figure 3b
Tafel slope104.49 mV dec-1Figure Axis
Rounded Reported
10896 · Results and Discussion · Figure 3c

linear sweep voltammetry and chronopotentiometry OER testing

NiFe-MOF NSs catalyst ink on glassy carbon · Electrode

O2-saturated 1 M KOH, three-electrode cell, Hg/HgO reference, carbon rod counter, GC disk working electrode, 1200 rpm, LSV 5 mV s^-1, iR-corrected

Temperature
room temperature
Atmosphere
O2-saturated electrolyte
Geometry
5 mm glassy carbon disk, rotating at 1200 rpm
Context
MOF/carbon black/Nafion catalyst ink
Measurement source
10893 · Electrochemical Measurements · Figure 3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
current density at 1.55 V vs RHEMarked as a best value within this paper48.57 mA cm-2 at 1.55 V vs RHEText
Exact Reported
10897 · Results and Discussion · Figure 3b
accelerated CV cycling stability test1000 cyclic voltammetry cyclesText
Exact Reported
10897 · Results and Discussion · Figure 3d
OER overpotential at 10 mA cm^-2Marked as a best value within this paper240 mV at 10 mA cm-2Text
Exact Reported
10897 · Results and Discussion · Figure 3a,b
chronopotentiometry durability at 10 mA cm^-2Marked as a best value within this paperstable potential for 16 hText
Exact Reported
10897 · Results and Discussion · Figure 3e
Tafel slopeMarked as a best value within this paper73.44 mV dec-1Text
Exact Reported
10897 · Results and Discussion · Figure 3c

linear sweep voltammetry OER testing

RuO2 benchmark catalyst ink on glassy carbon · Electrode

O2-saturated 1 M KOH, three-electrode cell, LSV 5 mV s^-1, iR-corrected

Temperature
room temperature
Atmosphere
O2-saturated electrolyte
Geometry
5 mm glassy carbon disk
Context
oxide/carbon black/Nafion catalyst ink
Measurement source
10896 · Results and Discussion · Figure 3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Tafel slope90.5 mV dec-1Text
Exact Reported
10897 · Results and Discussion · Figure 3c

zeta potential

NiFe-MOF bulk · Powder

Malvern Zetasizer Nano series analyser

Atmosphere
aqueous dispersion
Context
pristine framework powder dispersion
Measurement source
S25 · Supporting Information · Figure S23
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
NiFe-MOF bulk zeta potential5.41 mVCaption
Exact Reported
S25 · Supporting Information · Figure S23

zeta potential

NiFe-MOF NSs · Nanosheet

Malvern Zetasizer Nano series analyser

Atmosphere
aqueous dispersion
Context
pristine framework powder dispersion
Measurement source
S25 · Supporting Information · Figure S23
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
NiFe-MOF NS zeta potentialMarked as a best value within this paper31.0 mVCaption
Exact Reported
S25 · Supporting Information · Figure S23