Diffraction Structure — A Monocrystalline Coordination Polymer with Multiple Redox Centers as a High-Performance Cathode for Lithium-Ion Batteries

Measurement evidence

Diffraction Structure

A Monocrystalline Coordination Polymer with Multiple Redox Centers as a High-Performance Cathode for Lithium-Ion Batteries · Luo Y., Liu J., Zhang L. · Angewandte Chemie - International Edition · 2022 · e202209458

2 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

in situ XRD during first cycle

CuCA composite electrode in liquid-electrolyte LIB coin cell · Electrode

CuCA electrode cast on Be slice; Li metal anode; GFD separator; 1.0 M LiTFSI in DME/DOL; current density 100 mA g-1.

Geometry
operando XRD cell with 29 mm Be slice
Context
composite CuCA electrode
Measurement source
4 · In situ XRD test · Figure 5d; Figure S14
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
(201) XRD peak position tracked in situ28.45 deg28.45 deg 2thetaText
Exact Reported
6 · Results and Discussion · Figure 5d; Figure S14

powder X-ray diffraction with Rietveld refinement

as-synthesised CuCA nanosheet powder · Nanosheet

Cu K alpha radiation; refined monoclinic CuCA structure; comparison with calculated pattern.

Geometry
powder diffraction
Context
pristine CuCA powder
Measurement source
3 · Results and Discussion · Figure 2a; Table S2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Rietveld unit-cell aa = 9.26 A9.26 AText
Exact Reported
3 · Results and Discussion · Table S2
Rietveld unit-cell bb = 7.54 A7.54 AText
Exact Reported
3 · Results and Discussion · Table S2
Rietveld beta anglebeta = 98.91 deg98.91 degText
Exact Reported
3 · Results and Discussion · Table S2
Rietveld unit-cell cc = 5.02 A5.02 AText
Exact Reported
3 · Results and Discussion · Table S2
Rietveld unit-cell volumeV = 346.58 A3346.58 A3SI Table
Exact Reported
22 · Results and Discussion · Table S2
interlayer spacing for (201) plane3.13 A3.13 AText
Exact Reported
3 · Results and Discussion · Figure 2c
Rietveld RpRp = 3.74%3.74 %Text
Exact Reported
3 · Results and Discussion · Figure 2a
Rietveld RwpRwp = 5.10%5.1 %Text
Exact Reported
3 · Results and Discussion · Figure 2a
space groupPaText
Exact Reported
3 · Results and Discussion · Figure 2a; Table S2