Other — Photochromism and photomagnetism in three cyano-bridged 3d-4f heterobimetallic viologen frameworks

7 measurement groups · 15 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CoDy as-synthesised crystals · Single Crystal

2-300 K under 1000 Oe before and after 15 min xenon-light irradiation

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CoDy minimum chiMT before irradiation	4.06 cm3 mol-1 K at 2 K	—	—	Text Exact Reported	4963 · Photomagnetic properties · Fig. 5a
CoDy chiMT at 300 K after irradiation	6.92 cm3 mol-1 K at 300 K	—	—	Text Exact Reported	4964 · Photomagnetic properties · Fig. 5a
CoDy chiMT at 300 K before irradiation	6.02 cm3 mol-1 K at 300 K	—	—	Text Exact Reported	4963 · Photomagnetic properties · Fig. 5a
CoDy maximum chiMT after irradiationMarked as a best value within this paper	8.60 cm3 mol-1 K at 10 K	—	—	Text Exact Reported	4964 · Photomagnetic properties · Fig. 5a
CoDy chiMT increase at 300 K after irradiation	14.4%	—	—	Text Exact Reported	4964 · Photomagnetic properties · Fig. 5a

CoEu as-synthesised crystals · Single Crystal

2-300 K under 1000 Oe before and after 15 min xenon-light irradiation

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CoEu chiMT at 300 K before irradiation	0.56 cm3 mol-1 K	—	—	Text Exact Reported	4964 · Photomagnetic properties · Fig. 5b
CoEu chiMT increase at 300 K after irradiationMarked as a best value within this paper	about 16.3%	—	about	Text Approximate	4964 · Photomagnetic properties · Fig. 5b

FeDy as-synthesised crystals · Single Crystal

2-300 K under 1000 Oe before and after 15 min xenon-light irradiation

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
FeDy chiMT at 2 K before irradiation	5.71 cm3 K mol-1 at 2 K	—	—	Text Exact Reported	4964 · Photomagnetic properties · Fig. 5c
FeDy chiMT at room temperature before irradiation	6.66 cm3 mol-1 K	—	—	Text Exact Reported	4964 · Photomagnetic properties · Fig. 5c
FeDy maximum chiMT before irradiation	7.11 cm3 K mol-1 at 72 K	—	—	Text Exact Reported	4964 · Photomagnetic properties · Fig. 5c
FeDy chiMT increase at 300 K after irradiation	9.3% increase annotated in Fig. 5c	—	—	Figure Axis Rounded Reported	4964 · Photomagnetic properties · Fig. 5c

CoDy as-synthesised crystals · Single Crystal

as-synthesised crystals

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CoDy yield based on BCEbpy	52%	—	—	Text Exact Reported	4960 · Syntheses

CoEu as-synthesised crystals · Single Crystal

as-synthesised crystals

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CoEu yield based on BCEbpyMarked as a best value within this paper	68%	—	—	Text Exact Reported	4960 · Syntheses

FeDy as-synthesised crystals · Single Crystal

as-synthesised crystals

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
FeDy yield based on BCEbpy	65%	—	—	Text Exact Reported	4960 · Syntheses

CoDy as-synthesised crystals · Single Crystal

CoDy, CoEu and FeDy heated under N2 at 10 degC min-1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
TG curves recorded under nitrogen	TG curves of CoDy, CoEu and FeDy under N2 at 10 degC/min	—	—	Caption Exact Reported	4 · Thermo-gravimetric analysis · Figure S2