Spectroscopy — Multimetallic Prussian Blue Analogue Nanoparticles for Oxygen Evolution Reaction and Efficient Benzyl Alcohol Oxidation

Measurement evidence

Spectroscopy

Multimetallic Prussian Blue Analogue Nanoparticles for Oxygen Evolution Reaction and Efficient Benzyl Alcohol Oxidation · Singh B., Kumar R., Draksharapu A. · ACS Applied Nano Materials · 2024 · 15763-15771

3 measurement groups · 26 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

FTIR spectroscopy

MnFeCoNiCu-PBA nanoparticles · Powder

Fresh MnFeCoNiCu-PBA powder; SI spectrum not supplied locally

Context
pristine powder
Measurement source
15766 · Results and Discussion: Synthesis and Characterization of the Catalysts · Figure S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
FTIR C≡N stretch for MII-CN-FeII moiety2098 cm-1Text
Exact Reported
15766 · Results and Discussion · Figure S3
FTIR C≡N stretch for MII-CN-FeIII unit2163 cm-1Text
Exact Reported
15766 · Results and Discussion · Figure S3

ICP-AES elemental composition analysis

MnFeCoNiCu-PBA nanoparticles · Powder

ICP-AES wt% composition reported for fresh MnFeCoNiCu-PBA, MnFeCoNi-PBA, MnFeCo-PBA, MnFe-PBA, and MnFeCoNiCu-PBA after CA.

Context
fresh pristine PBA powders and post-chronoamperometry reconstructed sample
Measurement source
S5 · Supporting Information · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Fe content in MnFe-PBA14.89 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Mn content in MnFe-PBA11.89 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Co content in MnFeCo-PBA11.85 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Fe content in MnFeCo-PBA13.92 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Mn content in MnFeCo-PBA12.76 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Co content in MnFeCoNi-PBA10.32 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Fe content in MnFeCoNi-PBA14.21 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Mn content in MnFeCoNi-PBA11.34 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Ni content in MnFeCoNi-PBA11.21 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Co content in MnFeCoNiCu-PBA after CA8.11 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Cu content in MnFeCoNiCu-PBA after CA9.13 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Fe content in MnFeCoNiCu-PBA after CA10.12 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Mn content in MnFeCoNiCu-PBA after CA8.92 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Ni content in MnFeCoNiCu-PBA after CA7.96 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Co content in MnFeCoNiCu-PBA8.23 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Cu content in MnFeCoNiCu-PBA9.21 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Fe content in MnFeCoNiCu-PBA15.22 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Mn content in MnFeCoNiCu-PBA9.79 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1
Ni content in MnFeCoNiCu-PBA8.14 wt%SI Table
Exact Reported
S5 · Supporting Information · Table S1

X-ray photoelectron spectroscopy (XPS), PHI 5000 Versa Prob II

MnFeCoNiCu-PBA nanoparticles · Powder

Fresh MnFeCoNiCu-PBA prepared on a thin glass slide; data fitted using Origin Pro 8.5

Context
pristine powder
Measurement source
15764; 15766 · Characterization; Results and Discussion · Figure 2a-f
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Fresh Co 2p3/2 binding energy780.27 eVText
Exact Reported
15766 · Results and Discussion · Figure 2c
Fresh Cu 2p3/2 binding energy933.30 eVText
Exact Reported
15766 · Results and Discussion · Figure 2e
Fresh Fe 2p3/2 binding energy708.36 eVText
Exact Reported
15766 · Results and Discussion · Figure 2b
Fresh Mn 2p3/2 binding energy640.50 eVText
Exact Reported
15766 · Results and Discussion · Figure 2a
Fresh Ni 2p3/2 binding energy854.15 eVText
Exact Reported
15766 · Results and Discussion · Figure 2d