Spectroscopy

FTIR/NIR spectroscopy

NZMF powder / pristine bimetallic MOF · Powder

FTIR spectra of NZMF and NZMF/CF from 4000 to 400 cm^-1 per SI instrument description.

Geometry: powder and composite samples
Context: pristine and composite comparison
Measurement source: p007-p008 / article pp6037-6038 · Results and discussion · Figure 9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C-N vibrational incidence	1117 cm^-1	—	—	Text Rounded Reported	p008 / article p6038 · Results and discussion · Figure 9
CN-CHO vibrational incidence	714 cm^-1	—	—	Text Rounded Reported	p008 / article p6038 · Results and discussion · Figure 9
COO asymmetric/symmetric stretching range	1373 to 1627 cm^-1	—	—	Text Range	p007-p008 / article pp6037-6038 · Results and discussion · Figure 9
FTIR MOF coordination band range	1627 to 714 cm^-1	—	—	Text Range	p007-p008 / article pp6037-6038 · Results and discussion · Figure 9
NZMF/CF additional band	2326 to 2090 cm^-1	—	—	Text Range	p008 / article p6038 · Results and discussion · Figure 9
O-H stretching band	about 3430 cm^-1	—	—	Text Approximate	p008 / article p6038 · Results and discussion · Figure 9

Raman spectroscopy

NZMF powder / pristine bimetallic MOF · Powder

Raman spectra of NZMF and NZMF/CF; SI method gives 200-3000 cm^-1 range and 1.4 cm^-1 resolution.

Geometry: powder and composite samples
Context: pristine and composite comparison
Measurement source: p008 / article p6038 · Results and discussion · Figure 10

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Raman C-O vibration	1010 cm^-1	—	—	Text Rounded Reported	p008 / article p6038 · Results and discussion · Figure 10
Raman COO vibration	1472 cm^-1	—	—	Text Rounded Reported	p008 / article p6038 · Results and discussion · Figure 10
Raman band	1596 cm^-1	—	—	Text Rounded Reported	p008 / article p6038 · Results and discussion · Figure 10
Raman band	595 cm^-1	—	—	Text Rounded Reported	p008 / article p6038 · Results and discussion · Figure 10
benzene ring C-H bending Raman peak	821 cm^-1	—	—	Text Rounded Reported	p008 / article p6038 · Results and discussion · Figure 10
NZMF/CF increased intensity band	1346 cm^-1	—	—	Text Rounded Reported	p008 / article p6038 · Results and discussion · Figure 10
NZMF/CF increased intensity band	1590 cm^-1	—	—	Text Rounded Reported	p008 / article p6038 · Results and discussion · Figure 10

X-ray photoelectron spectroscopy (XPS)

X-ray photoelectron spectroscopy

NZMF powder / pristine bimetallic MOF · Powder

Ni 2p, Zn 2p, O 1s and C 1s spectra for NZMF and NZMF/CF; SI survey scan noted.

Geometry: powder and CF-supported samples
Context: pristine and composite comparison
Measurement source: p004-p007 / article pp6034-6037 · Results and discussion · Figure 8 and Fig. S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C 1s sp2 C-C peak	284.4 eV	—	—	Text Exact Reported	p007 / article p6037 · Results and discussion · Figure 8D
C 1s C-O peak	286 eV	—	—	Text Rounded Reported	p007 / article p6037 · Results and discussion · Figure 8D
C 1s O-C-O peak	287.8 eV	—	—	Text Exact Reported	p007 / article p6037 · Results and discussion · Figure 8D
C 1s sp2 hybridisation peak in CF	284.6 eV	—	—	Text Exact Reported	p007 / article p6037 · Results and discussion · Figure 8D
C 1s sp3 hybridisation peak	288.5 eV	—	—	Text Exact Reported	p007 / article p6037 · Results and discussion · Figure 8D
NZMF Ni 2p1/2 binding energy	873.69 eV	—	—	Text Exact Reported	p004 / article p6034 · Results and discussion · Figure 8A
NZMF Ni 2p3/2 binding energy	856.24 eV	—	—	Text Exact Reported	p004 / article p6034 · Results and discussion · Figure 8A
NZMF Ni satellite/outpost peak	861.9 eV	—	—	Text Rounded Reported	p004 / article p6034 · Results and discussion · Figure 8A
NZMF Ni satellite/outpost peak	879.8 eV	—	—	Text Rounded Reported	p004 / article p6034 · Results and discussion · Figure 8A
NZMF O 1s peak	531.59 eV	—	—	Text Exact Reported	p007 / article p6037 · Results and discussion · Figure 8C
NZMF O 1s peak	532.81 eV	—	—	Text Exact Reported	p007 / article p6037 · Results and discussion · Figure 8C
NZMF/CF adsorbed water O 1s peak	531.62 eV	—	—	Text Exact Reported	p007 / article p6037 · Results and discussion · Figure 8C
NZMF/CF C-O/surface hydroxyl O 1s peak	532.13 eV	—	—	Text Exact Reported	p007 / article p6037 · Results and discussion · Figure 8C
NZMF/CF metal-oxygen O 1s peak	532.11 eV	—	—	Text Exact Reported	p007 / article p6037 · Results and discussion · Figure 8C
NZMF/CF oxygen in metal O 1s peak	532.75 eV	—	—	Text Exact Reported	p007 / article p6037 · Results and discussion · Figure 8C
SI XPS survey confirms NZMF and NZMF/CF elemental signals	XPS survey scan of NZMF and NZMF/CF samples; Ni, Zn, O and C signals present	—	—	Visual Estimate Qualitative	p003 · Supplementary file · Fig. S1
Zn 2p1/2 binding energy	1045.24 eV	—	—	Text Exact Reported	p007 / article p6037 · Results and discussion · Figure 8B
Zn 2p3/2 binding energy	1022.15 eV	—	—	Text Exact Reported	p007 / article p6037 · Results and discussion · Figure 8B
Zn 2p spin-orbit splitting	23.09 eV	—	—	Text Exact Reported	p007 / article p6037 · Results and discussion · Figure 8B

3 measurement groups · 32 results