Electrochemistry Application — Soluble semi-conductive chelate polymers containing Cr(III) in the backbone: Synthesis, characterization, optical, electrochemical, and electrical properties

Measurement evidence

Electrochemistry Application

Soluble semi-conductive chelate polymers containing Cr(III) in the backbone: Synthesis, characterization, optical, electrochemical, and electrical properties · Yildirim M., Kaya I. · Polymer · 2009 · 5653-5660

1 measurement group · 15 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

cyclic voltammetry

P-1 as-synthesised polymer · Powder

CHI 660 C analyser, 20 mV/s, dry argon box at room temperature, Pt working/counter electrodes, Ag reference calibrated vs Fc/Fc+, DMSO/acetonitrile 1/4 with TBAPF6 electrolyte

Temperature: room temperature
Atmosphere: argon
Geometry: platinum working electrode, Ag reference, platinum counter electrode
Context: pristine polymers
Measurement source: 5654; 5656-5657 (p002, p004-p005) · 2.4 Optical and electrochemical properties; 3.3 Optical and electrochemical properties · Figure 4; Table 3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
P-1 oxidation peak potential	1.39 V	—	—	Text Exact Reported	5656 (p004) · 3.3 Optical and electrochemical properties · Figure 4a
P-1 reduction peak potential	-0.89 V	—	—	Text Exact Reported	5656 (p004) · 3.3 Optical and electrochemical properties · Figure 4a
P-1 electrochemical band gap Eg prime	2.28 eV	—	—	Table Exact Reported	5657 (p005) · 3.3 Optical and electrochemical properties · Table 3
P-1 HOMO energy	-5.78 eV	—	—	Table Exact Reported	5657 (p005) · 3.3 Optical and electrochemical properties · Table 3
P-1 LUMO energy	-3.50 eV	—	—	Table Exact Reported	5657 (p005) · 3.3 Optical and electrochemical properties · Table 3
P-2 oxidation peak potential	1.43 V	—	—	Text Exact Reported	5656 (p004) · 3.3 Optical and electrochemical properties · Figure 4a
P-2 reduction peak potential	-0.55 V	—	—	Text Exact Reported	5656 (p004) · 3.3 Optical and electrochemical properties · Figure 4a
P-2 electrochemical band gap Eg primeMarked as a best value within this paper	1.98 eV	—	—	Table Exact Reported	5657 (p005) · 3.3 Optical and electrochemical properties · Table 3
P-2 HOMO energy	-5.82 eV	—	—	Table Exact Reported	5657 (p005) · 3.3 Optical and electrochemical properties · Table 3
P-2 LUMO energy	-3.84 eV	—	—	Table Exact Reported	5657 (p005) · 3.3 Optical and electrochemical properties · Table 3
P-3 oxidation peak potential	1.41 V	—	—	Text Exact Reported	5656 (p004) · 3.3 Optical and electrochemical properties · Figure 4a
P-3 reduction peak potential	-0.73 V	—	—	Text Exact Reported	5656 (p004) · 3.3 Optical and electrochemical properties · Figure 4a
P-3 electrochemical band gap Eg prime	2.14 eV	—	—	Table Exact Reported	5657 (p005) · 3.3 Optical and electrochemical properties · Table 3
P-3 HOMO energy	-5.80 eV	—	—	Table Exact Reported	5657 (p005) · 3.3 Optical and electrochemical properties · Table 3
P-3 LUMO energy	-3.66 eV	—	—	Table Exact Reported	5657 (p005) · 3.3 Optical and electrochemical properties · Table 3