Electrical Transport — Mixed Anionic and Cationic Redox Chemistry in a Tetrathiomolybdate Amorphous Coordination Framework

2 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

<Na2MoS4> cold-pressed pellet · Pellet

Two-probe DC I-V from 0.01 to -0.01 V at 2 mV s-1; EIS from 10^6 to 0.1 Hz; temperatures -60 to 80 C in 20 C steps with 30 min stabilisation.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
<Na2MoS4> direct ionic conductivity not resolved	assumed ion conducting but at lower magnitudes than electrical conduction	—	—	Text Qualitative	6 (16584) · Results and Discussion · Figure 5
<Na2MoS4> electronic conductivity at 20 CMarked as a best value within this paper	sigma_eon as high as 6.1 x 10^-4 S cm^-1 at 20 C	0.00061 S cm-1	—	Text Rounded Reported	5 (16583) · Results and Discussion · Figure 5
<Na2MoS4> electronic activation energyMarked as a best value within this paper	<Na2MoS4>_eon = 136 meV	—	—	Text Exact Reported	6 (16584) · Results and Discussion · Figure 5

Na2MoS4.3.5H2O cold-pressed pellet · Pellet

Two-probe DC I-V and EIS over -60 to 80 C; EIS fitted with transmission-line model to separate ionic and electronic rails.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Na2MoS4.3.5H2O electronic conductivity at 20 C	sigma_eon = 9.27 x 10^-8 S cm^-1 at 20 C	9.27e-8 S cm-1	—	Text Exact Reported	6 (16584) · Results and Discussion · Figure 5
Na2MoS4.3.5H2O electronic activation energy	Na2MoS4.3.5H2O_eon = 742 meV	—	—	Text Exact Reported	6 (16584) · Results and Discussion · Figure 5
Na2MoS4.3.5H2O ionic activation energy	Na2MoS4.3.5H2O_ion = 986 meV	—	—	Text Exact Reported	6 (16584) · Results and Discussion · Figure 5
Na2MoS4.3.5H2O ionic conductivity at 20 C	sigma_ion = 1.35 x 10^-6 S cm^-1 at 20 C	0.00000135 S cm-1	—	Text Exact Reported	6 (16584) · Results and Discussion · Figure 5