cMOF Evidence Base
Diffraction Structure — Spindle-like Ni3(HITP)2 MOFs: Synthesis and Li+ storage mechanism

Measurement evidence

Diffraction Structure

Spindle-like Ni3(HITP)2 MOFs: Synthesis and Li+ storage mechanism · Zhang Y., Qiu T., Jiang F. et al. · Applied Surface Science · 2021 · 149818

2 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Ex situ XRD and SEM before/after charging and after cycling

X-ray diffraction and scatteringScanning electron microscopy

Ni3(HITP)2 electrode on copper foil · Electrode

Film electrodes on Cu foil before and after charge were characterised by XRD; SEM before charge and after 10 charge/discharge cycles.

Geometry
electrode film on Cu foil
Context
composite electrode; supporting SI figures only captioned in supplied SI text
Measurement source
2-3 · Supplementary data · Figures S3-S4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
SEM morphology after 10 cyclesspindle morphology maintained well after 10 cycles——Text
Qualitative		3 · Supplementary data · Figure S4
ex situ electrode XRD conductive carbon peak26.5 degrees 2-theta, attributed to conductive carbon——Text
Exact Reported		5 · Results and discussion · Figure S3
ex situ electrode XRD metallic Cu peak43.3 degrees 2-theta, related to metallic Cu from Cu foil collector——Text
Exact Reported		5 · Results and discussion · Figure S3
ex situ electrode XRD CuOx peak18.2 degrees 2-theta, related to CuOx from Cu foil collector——Text
Exact Reported		5 · Results and discussion · Figure S3
XRD after charge structural retentionXRD patterns before and after charge are similar; Ni3(HITP)2 peaks between 4.7 and 15 degrees retained——Text
Qualitative		2 · Supplementary data · Figure S3

Powder X-ray diffraction (XRD, Empyrean Bruker D8)

X-ray diffraction and scattering

as-prepared Ni3(HITP)2 MOF powder · Powder

XRD pattern of as-prepared Ni3(HITP)2 MOFs compared with simulated/literature values.

Geometry
powder
Context
pristine framework powder
Measurement source
4 · Results and discussion · Fig. 2d
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
(001) facet d spacing0.33 nm——Text
Exact Reported		4 · Results and discussion · Fig. 2d
XRD peak12.6 degrees 2-theta——Text
Exact Reported		4 · Results and discussion · Fig. 2d
XRD peak16.5 degrees 2-theta——Text
Exact Reported		4 · Results and discussion · Fig. 2d
XRD peak indexed to (001)27.1 degrees 2-theta——Text
Exact Reported		4 · Results and discussion · Fig. 2d
XRD peak33.3 degrees 2-theta——Text
Exact Reported		4 · Results and discussion · Fig. 2d
XRD peak indexed to (100)4.7 degrees 2-theta——Text
Exact Reported		4 · Results and discussion · Fig. 2d
XRD peak indexed to (200)9.5 degrees 2-theta——Text
Exact Reported		4 · Results and discussion · Fig. 2d